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94141

4-Chloro-α-cyanocinnamic acid

Name: 4-Chloro-α-cyanocinnamic acid
Brand: SIAL

matrix substance for MALDI-MS, ≥95.0% (HPLC)

别名:

3-(4-Chlorophenyl)-2-cyano-2-propenoic acid, 3-(4-Chlorophenyl)-2-cyanoacrylic acid, p-Chloro-α-cyanocinnamic acid, p-Chlorobenzylidenecyanoacetic acid, ClCCA, NSC 2479

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About This Item

经验公式（希尔记法）:

C₁₀H₆ClNO₂

CAS号:

69727-07-7

分子量:

207.61

Beilstein:

2616773

MDL编号:

MFCD02317172

UNSPSC代码:

12000000

PubChem化学物质编号:

329770304

NACRES:

NA.21

等级

matrix substance for MALDI-MS

质量水平

100

检测方案

≥95.0% (HPLC)

形式

crystals

分析物功能类别

drugs of abuse, ionic liquids

分析物化学类别

chlorinated lipids, lipids, peptides, phospholipids, phosphopeptides

技术

MALDI-MS: suitable

溶解性

methanol: 100 mg/10 mL, clear, colorless to light yellow

SMILES字符串

OC(=O)\C(=C\c1ccc(Cl)cc1)C#N

InChI

1S/C10H6ClNO2/c11-9-3-1-7(2-4-9)5-8(6-12)10(13)14/h1-5H,(H,13,14)/b8-5+

InChI key

MXCRRKYUQNHWLJ-VMPITWQZSA-N

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应用

suitable as MALDI-Matrix material
suitable for collision-induced dissociation MS/MS (CID-MS/MS)

警示用语：

Danger

危险声明

H301,H312 + H332

预防措施声明

P261 - P264 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P312

危险分类

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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分析证书(COA)

Lot/Batch Number

BCBL7698V

BCBL7698

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MALDI-TOF-MS analysis of sialylated glycans and glycopeptides using 4-chloro-α-cyanocinnamic acid matrix.

Maurice H J Selman et al.

Proteomics, 12(9), 1337-1348 (2012-05-17)

For MALDI analysis of glycans and glycopeptides, the choice of matrix is crucial in minimizing desialylation by mass spectrometric in-source and metastable decay. Here, we evaluated the potential of 4-chloro-α-cyanocinnamic acid (Cl-CCA) for MALDI-TOF-MS analysis of labile sialylated tryptic N-glycopeptides

Identification of multiphosphorylated peptides in milk.

Florian Baum et al.

Journal of agricultural and food chemistry, 61(38), 9110-9117 (2013-09-03)

Multiphosphorylated peptides endogenously present in milk exert anticariogenic activity due to their calcium binding capacity. This study performed comprehensive analysis of multiphosphorylated peptides in raw milk using matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS). Since phosphopeptides are often negatively

Alternative CHCA-based matrices for the analysis of low molecular weight compounds by UV-MALDI-tandem mass spectrometry.

Tiffany Porta et al.

Journal of mass spectrometry : JMS, 46(2), 144-152 (2011-01-25)

Analysis of low molecular weight compounds (LMWC) in complex matrices by vacuum matrix-assisted laser desorption/ionization (MALDI) often suffers from matrix interferences, which can severely degrade limits of quantitation. It is, therefore, useful to have available a range of suitable matrices

Evaluation of the new MALDI matrix 4-chloro-alpha-cyanocinnamic acid.

John D Leszyk

Journal of biomolecular techniques : JBT, 21(2), 81-91 (2010-07-02)

MALDI-TOF continues to be an important tool for many proteomic studies. Recently, a new rationally designed matrix 4-chloro-alpha-cyanocinnamic acid was introduced, which is reported to have superior performance as compared with the "gold standard" alpha-cyano-4-hydroxycinnamic acid (CHCA). In this study

Compelling evidence for Lucky Survivor and gas phase protonation: the unified MALDI analyte protonation mechanism.

Thorsten W Jaskolla et al.

Journal of the American Society for Mass Spectrometry, 22(6), 976-988 (2011-09-29)

This work experimentally verifies and proves the two long since postulated matrix-assisted laser desorption/ionization (MALDI) analyte protonation pathways known as the Lucky Survivor and the gas phase protonation model. Experimental differentiation between the predicted mechanisms becomes possible by the use

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