901409
[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6
solid
别名:
铱 (III) 双 [2-（2,4-二氟苯基）-5-甲基吡啶- N ,C 20 ]-4,40-二- 叔 -丁基-2,20-二吡啶六氟磷酸盐
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关于此项目
经验公式（希尔记法）:
C42H40F10IrN4P
化学文摘社编号:
分子量:
1013.97
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22
产品名称
[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6,
InChI key
XAJPUJWOMJJPNU-UHFFFAOYSA-N
form
solid
reaction suitability
core: iridium
reaction type: Photocatalysis
reagent type: catalyst
photocatalyst activation
450 nm
Quality Level
Application
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
Sébastien Ladouceur et al.
Inorganic chemistry, 50(22), 11514-11526 (2011-10-04)
Herein we report the synthesis of 4-aryl-1-benzyl-1H-1,2,3-triazoles (atl), made via "Click chemistry" and their incorporation as cyclometallating ligands into new heteroleptic iridium(III) complexes containing diimine (N(^)N) ancillary ligands 2,2'-bipyridine (bpy) and 4,4'-di-tert-butyl-2,2'-bipyridine (dtBubpy). Depending on decoration, these complexes emit from
Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S, et al.
European Journal of Inorganic Chemistry, 2013(30), 5329-5343 (2013)
Andrew J Musacchio et al.
Science (New York, N.Y.), 355(6326), 727-730 (2017-02-18)
The intermolecular hydroamination of unactivated alkenes with simple dialkyl amines remains an unsolved problem in organic synthesis. We report a catalytic protocol for efficient additions of cyclic and acyclic secondary alkyl amines to a wide range of alkyl olefins with
Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
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