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Merck
CN
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文件

901368

Sigma-Aldrich

[Ir(dFppy)2(dtbbpy)]PF6

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经验公式（希尔记法）:
C40H36F10IrN4P
CAS号:
1072067-44-7
分子量:
985.92
NACRES:
NA.23

形式

powder or crystals

质量水平

100

反应适用性

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

光触媒活化

465 nm

相关类别

应用

这种光催化剂很易于促进羧酸的烷化作用，以及通过金属光氧化还原催化的草酸脱羧交叉偶联。

产品可以和我们的光反应器一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

其他说明

相关产品

产品编号
说明
价格

747769

[Ir(dtbbpy)(ppy)2]PF6

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

804215

[Ir{dFCF3ppy}2（bpy）]PF6

900540

Ir(dFppy)3

900539

铱 [ p -F (t-Bu)-ppy] 3

900538

Ir(p-F-ppy)3

900570

Ir[dF(t-Bu)-ppy]3

901409

[铱 (dF (Me) ppy)] 2 (dtbbpy) ] PF 6

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6, ≥95%

904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

分析证书(COA)

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Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S,et al.
European Journal of Inorganic Chemistry, 2013, 5329-5343 (2013)
Franck Le Vaillant et al.
Angewandte Chemie (International ed. in English), 54(38), 11200-11204 (2015-07-28)
Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes from readily available carboxylic
Xiaheng Zhang et al.
Journal of the American Chemical Society (2016-10-11)
Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to
Timothy M Monos et al.
The Journal of organic chemistry, 81(16), 6988-6994 (2016-06-16)
We report a rapid, one-pot, operationally simple, and scalable preparation of valuable cationic heteroleptic iridium(III) polypyridyl photosensitizers. This method takes advantage of two consecutive microwave irradiation steps in the same reactor vial, avoiding the need for additional reaction purifications. A

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