901368
[Ir(dFppy)2(dtbbpy)]PF6
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关于此项目
经验公式（希尔记法）:
C40H36F10IrN4P
化学文摘社编号:
分子量:
985.92
MDL number:
UNSPSC Code:
51171641
NACRES:
NA.23
InChI
1S/C18H24N2.2C11H6F2N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-4,6-7H;;/q;;;-1;+5
InChI key
QHIBKCJQTBUWRW-UHFFFAOYSA-N
SMILES string
[Ir+3]5([n+]6c(cc(cc6)C(C)(C)C)c7[n+]5ccc(c7)C(C)(C)C)(c3c(c(cc(c3)F)F)c4ncccc4)c1c(c(cc(c1)F)F)c2ncccc2.F[P-](F)(F)(F)(F)F
form
powder or crystals
reaction suitability
core: iridium
reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
photocatalyst activation
465 nm
Quality Level
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S,et al.
European Journal of Inorganic Chemistry, 2013, 5329-5343 (2013)
Franck Le Vaillant et al.
Angewandte Chemie (International ed. in English), 54(38), 11200-11204 (2015-07-28)
Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes from readily available carboxylic
Timothy M Monos et al.
The Journal of organic chemistry, 81(16), 6988-6994 (2016-06-16)
We report a rapid, one-pot, operationally simple, and scalable preparation of valuable cationic heteroleptic iridium(III) polypyridyl photosensitizers. This method takes advantage of two consecutive microwave irradiation steps in the same reactor vial, avoiding the need for additional reaction purifications. A
Xiaheng Zhang et al.
Journal of the American Chemical Society (2016-10-11)
Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to
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