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922897

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆

Name: [Ir(ppy)2(5,5&#8242;-Me2bpy)]PF6
Brand: ALDRICH

≥95%, powder

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关于此项目

经验公式（希尔记法）:

C₃₄H₂₈F₆IrN₄P

化学文摘社编号:

808142-82-7

分子量:

829.79

MDL number:

MFCD34602233

UNSPSC Code:

12352101

NACRES:

NA.22

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属性

产品名称

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆, ≥95%

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned

SMILES string

[Ir+]741([NH]8=C(c9c7cccc9)C=CC=C8)([NH]5=CC=CC=C5c6c4cccc6)[NH]2=CC(=CC=C2C3=CC=C(C=[NH]31)C)C.F[P-](F)(F)(F)(F)F

InChI

1S/C12H12N2.2C11H8N.F6P.Ir/c1-9-3-5-11(13-7-9)12-6-4-10(2)8-14-12;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h3-8H,1-2H3;2*1-6,8-9H;;/q;;;-1;+1

InChI key

JFNHYYZGRBJZIH-UHFFFAOYSA-N

说明

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

[Ir(ppy)₂(5,5′-Me₂bpy)]PF₆ is a photoredox catalyst used for a variety of transformations.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

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Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity.

Nicholas A Till et al.

Journal of the American Chemical Society, 142(37), 15830-15841 (2020-08-14)

The combined use of reaction kinetic analysis, ultrafast spectroscopy, and stoichiometric organometallic studies has enabled the elucidation of the mechanistic underpinnings to a photocatalytic C-N cross-coupling reaction. Steady-state and ultrafast spectroscopic techniques were used to track the excited-state evolution of

全球贸易项目编号

货号	GTIN
922897-100MG	04065266894875
922897-500MG	04065266894882