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Merck
CN

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

solid

别名:

（Ir{dF（CF3）PPY}2（dtbpy））PF6, [4,4′-双（1,1-二甲基乙基）-2,2′-联吡啶N1，N1′]双[3,5-二氟-2- [5-（三氟甲基）-2-吡啶基N]苯基-C]六氟磷酸铱（III）

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关于此项目

经验公式（希尔记法）:
C42H34F16IrN4P
化学文摘社编号:
870987-63-6
分子量:
1121.91
MDL number:
MFCD27952556
UNSPSC Code:
12161600
NACRES:
NA.22

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产品名称

(Ir[dF(CF3)ppy]2(dtbpy))PF6,

SMILES string

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

form

solid

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

450 nm

Quality Level

100

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相关类别

Application

（Ir[DF（CF3）PPY]2（dtbpy））PF6 是一种环金属化的铱（III）配合物，可用于可见光介导的光催化有机转化。它可用于将烷基通过后期结合至多种生物活性杂环中。

产品可与我们的光反应器系列一起使用。包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000466653
0000466653
0000458158
0000458158
0000432515

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Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.
Teegardin K, et al.
Organic Process Research & Development, 20(7), 1156-1163 (2016)
A photochemical strategy for lignin degradation at room temperature.
Nguyen J D, et al.
Journal of the American Chemical Society, 136(4), 1218-1221 (2014)
Formal Total Synthesis of l-Ossamine via Decarboxylative Functionalization Using Visible-Light-Mediated Photoredox Catalysis in a Flow System.
Inuki S, et al.
The Journal of Organic Chemistry, 82(2), 1248-1253 (2017)
Radical Carbon?Carbon Bond Formations Enabled by Visible Light Active Photocatalysts.
Wallentin C J, et al.
Chimia, 66(6), 394-398 (2012)
Late?Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis.
DiRocco D A et al.
Angewandte Chemie (International Edition in English), 53(19), 4802-4806 (2014)

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