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905518

Sigma-Aldrich

Ir(dFFppy)2(dtbbpy)PF6

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About This Item

经验公式（希尔记法）:
C40H34F12IrN4P
CAS号:
2042201-18-1
分子量:
1021.90
MDL编号:
MFCD31807347
UNSPSC代码:
12161600
NACRES:
NA.22

表单

solid

反应适用性

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

光触媒活化

465 nm

SMILES字符串

FC1=C(C2=NC=C(F)C=C2)C([Ir]3([N]4=CC=C(C(C)(C)C)C=C4C5=CC(C(C)(C)C)=CC=[N]53)C6=CC(F)=CC(F)=C6C7=CC=C(F)C=N7)=CC(F)=C1.FP(F)(F)(F)(F)F

相关类别

应用

Ir(dFFppy)2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

其他说明

Metallaphotoredox-catalysed sp3–sp3cross-coupling of carboxylic acids with alkyl halides

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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分析证书(COA)

Lot/Batch Number
MKCS1997

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Craig P Johnston et al.
Nature, 536(7616), 322-325 (2016-08-19)
In the past 50 years, cross-coupling reactions mediated by transition metals have changed the way in which complex organic molecules are synthesized. The predictable and chemoselective nature of these transformations has led to their widespread adoption across many areas of

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