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Merck
CN
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文件

安全信息

674575

Sigma-Aldrich

MacMillan Imidazolidinone OrganoCatalysts™ 试剂盒 I

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所有图片(1)
UNSPSC代码:
12352005
eCl@ss:
32161000
NACRES:
NA.22

一般描述

MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and robust in simple reaction conditions because of their insensitivity to air and moisture.

应用

MacMillan Imidazolidinone organocatalysts can be used to catalyze various organocatalytic transformation reactions such as 1,3-dipolar cycloadditions, Diels–Alder reaction, Friedel-Crafts alkylations, α-chlorinations, α-fluorinations, and intramolecular Michael reactions to access a high level of enantioselective products. It can also be used in enantioselective photocatalytic reactions, hydride reduction, and Mukaiyama-Michael reaction.

法律信息

适用美国专利 6,369,243 和相关专利。仅供研究使用。

试剂盒组分也可单独购买

产品编号
说明
化学品安全说明书
  • 569763(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97% 500 mg化学品安全说明书
  • 661902(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid, 96% 500 mg化学品安全说明书
  • 663085(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid, 97% 500 mg化学品安全说明书
  • 663107(2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone, 97% 500 mg化学品安全说明书
  • 668540(2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone, 95% 250 mg化学品安全说明书

象形图

Skull and crossbonesCorrosion
GHS06,GHS05

警示用语：

Danger

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
advanced synthesis and catalysis, 363(3), 629-656 (2021)
Imidazolidinones as Asymmetric Organocatalysts
Sustainable Catalysis: Without Metals or Other Endangered Elements (2015)
Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
Advanced Synthesis & Catalysis, 363(3), 629-656 (2021)

商品

Macmillan Imidazolidinone Organocatalysts

Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.

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