661902
(S)-(+)-2-(叔丁基)-3-甲基-4-咪唑烷酮三氟乙酸
96%
别名:
(S)-(+)-2-(叔丁基)-3-甲基-4-氧代咪唑啉鎓三氟乙酸盐, (S)-2-(叔丁基)-3-甲基-4-咪唑烷酮三氟乙酸盐
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选择尺寸
关于此项目
经验公式（希尔记法）:
C10H17N2O3F3
化学文摘社编号:
分子量:
270.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
(S)-(+)-2-(叔丁基)-3-甲基-4-咪唑烷酮三氟乙酸, 96%
InChI
1S/C8H16N2O.C2HF3O2/c1-8(2,3)7-9-5-6(11)10(7)4;3-2(4,5)1(6)7/h7,9H,5H2,1-4H3;(H,6,7)/t7-;/m0./s1
SMILES string
OC(=O)C(F)(F)F.CN1[C@H](NCC1=O)C(C)(C)C
InChI key
HKHKOEMMPVPVOS-FJXQXJEOSA-N
assay
96%
form
solid
mp
99-103 °C
functional group
carboxylic acid
fluoro
Quality Level
Application
1,3-偶极加成反应和 Friedel-Crafts 烷基化反应的高选择性有机催化剂。
Legal Information
适用美国专利 6,369,243 和相关专利。仅供研究使用。
General description
(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid is a Macmillan imidazolidinone organocatalyst, which is generally employed in asymmetric transformation reactions.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Highly enantioselective transfer hydrogenation of alpha, beta-unsaturated ketones
Martin NJA and List B
Journal of the American Chemical Society, 128(41), 13368-13369 (2006)
New strategies in organic catalysis: the first enantioselective organocatalytic Friedel-Crafts alkylation.
N A Paras et al.
Journal of the American Chemical Society, 123(18), 4370-4371 (2001-07-18)
Jen, W. S. et al
Journal of the American Chemical Society, 122, 9874-9874 (2000)
Modern strategies in organic catalysis: the advent and development of iminium activation.
Lelais G and MacMillan DWC.
Aldrichimica Acta, 39(3), 79-87 (2006)
商品
Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.
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