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668540

Sigma-Aldrich

(2S,5S)-(–)-5-苄基-3-甲基-2-(5-甲基-2-呋喃基)-4-咪唑烷酮

95%

别名:

(2S,5S)-3-甲基-2-(5-甲基-2-呋喃基)-5-(苯甲基)-4-咪唑烷酮

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25 MG
CN¥1,956.58

CN¥1,956.58

预计发货时间June 16, 2025详情

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25 MG
CN¥1,956.58

About This Item

经验公式（希尔记法）:
C16H18N2O2
CAS号:
415678-40-9
分子量:
270.33
MDL编号:
MFCD08457653
UNSPSC代码:
12352005
PubChem化学物质编号:
24884991
NACRES:
NA.22

CN¥1,956.58

预计发货时间June 16, 2025详情

获取大包装报价

质量水平

100

方案

95%

折射率

n20/D 1.5598

官能团

phenyl

SMILES字符串

CN1[C@H](N[C@@H](Cc2ccccc2)C1=O)c3ccc(C)o3

InChI

1S/C16H18N2O2/c1-11-8-9-14(20-11)15-17-13(16(19)18(15)2)10-12-6-4-3-5-7-12/h3-9,13,15,17H,10H2,1-2H3/t13-,15-/m0/s1

InChI key

IQIMPHPFMHVWBZ-ZFWWWQNUSA-N

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form

solid

form

solid

form

solid

form

solid

manufacturer/tradename

Calbiochem®

manufacturer/tradename

-

manufacturer/tradename

Calbiochem®

manufacturer/tradename

Calbiochem®

Quality Level

100

Quality Level

-

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

solubility

DMSO: 100 mg/mL

solubility

DMSO: >5 mg/mL

solubility

DMSO: 100 mg/mL, ethanol: 20 mg/mL

solubility

DMSO: 50 mg/mL

应用

用于和简单 α,β-不饱和酮发生 Diels-Alder 反应的高选择性有机催化剂。[1]
Catalyst for:
  • Enantioselective organocatalytic transfer hydrogenation of cycloalkenones with tert-Bu Hantzsch ester as source of hydrogen
  • Alkylation of indoles with an α,β-disubstituted α,β-unsaturated aldehyde in the enantioselective preparation of a selective serotonin reuptake inhibitor
  • MacMillan reaction

法律信息

适用美国专利 6,369,243 和相关专利。仅供研究使用。

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险分类

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

>230.0 °F

闪点(°C)

> 110 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

    • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number
    MKCS1599
    MKBJ0030V
    MKBH3360V
    MKBG5800V
    10929BJ

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    Burk, M. J. et al
    Journal of the American Chemical Society, 118, 5142-5142 (1996)

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