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蒸汽密度
7.6 (vs air)
质量水平
蒸汽压
<0.01 mmHg ( 20 °C)
等级
purum
检测方案
≥99.0% (GC)
自燃温度
878 °F
bp
265 °C (lit.)
mp
68-72 °C
69-73 °C (lit.)
溶解性
methanol: 0.1 g/mL, clear, colorless
methanol: soluble 100 mg/mL, clear, colorless
SMILES字符串
Cc1cc(c(O)c(c1)C(C)(C)C)C(C)(C)C
InChI
1S/C15H24O/c1-10-8-11(14(2,3)4)13(16)12(9-10)15(5,6)7/h8-9,16H,1-7H3
InChI key
NLZUEZXRPGMBCV-UHFFFAOYSA-N
基因信息
human ... CAPN1(823)
rat ... Capn1(29153) , Nos1(24598)
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一般描述
2,6-二-叔丁基-4-甲基苯酚是一种 4-烷基酚。它是一种抗氧化剂，并表现出通过氧化代谢介导的亲电醌甲醚毒性。它作为 Michael 受体，它与单亲核体和蛋白质的反应已被报道。2,6-二- 叔丁基-4-甲基苯酚与铕 (II)-二苯甲酮二阴离子配合物的反应已有报道。食品添加剂 2,6-二--叔 -丁基-4-甲酚可促进小鼠急性肺毒性和肿瘤生长。
应用
2,6-二- 叔 -丁基-4-甲酚可用于制备有机铝化合物甲基铝双（2,6-二- 叔 -丁基-4-烷基酚氧化物）。
警示用语：
Warning
危险声明
预防措施声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1
WGK
WGK 2
闪点(°F)
260.6 °F
闪点(°C)
127 °C
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Methylaluminum bis (2, 6-di-tert-butyl-4-alkylphenoxide). A new reagent for obtaining unusual equatorial and anti-Cram selectivity in carbonyl alkylation.
Maruoka K, et al.
Journal of the American Chemical Society, 107(15), 4573-4576 (1985)
M A Lewis et al.
Chemical research in toxicology, 9(8), 1368-1374 (1996-12-01)
4-Alkylphenols, such as the antioxidant 2, 6-di-tert-butyl-4-methylphenol (BHT), exhibit toxicities that appear to be mediated by their oxidative metabolism to electrophilic quinone methides. Reactions of these Michael acceptors with simple nucleophiles and proteins have been reported, but little information is
Rene Kupfer et al.
Chemical research in toxicology, 15(8), 1106-1112 (2002-08-20)
Acute pulmonary toxicity and tumor promotion by the food additive 2,6-di-tert-butyl-4-methylphenol (BHT) in mice are well documented. These effects have been attributed to either of two quinone methides, 2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dienone (BHT-QM) formed through direct oxidation of BHT by pulmonary cytochrome P450
Novel crystal structure of ytterbium (II)-benzophenone dianion complex and its reaction with 2, 6-di-tert-butyl-4-methylphenol.
Hou Z, et al.
Journal of the Chemical Society. Chemical Communications, 9, 722-724 (1999)
A M Vijesh et al.
European journal of medicinal chemistry, 46(11), 5591-5597 (2011-10-05)
In the present study two new series of Hantzsch 1,4-dihydropyridine derivatives (1,4-DHPs) containing substituted pyrazole moiety (4a-f and 5a-f) were synthesized by the reaction of 3-aryl-1H-pyrazole-4-carbaldehydes with 1,3-dicarbonylcompounds (ethylacetoacetate and methylacetoacetate) and ammonium acetate. The newly synthesized compounds were characterized
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