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Merck
CN

928305

Sigma-Aldrich

cataCXium® A Pd G3 ChemBeads

别名:

Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3

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About This Item

经验公式(希尔记法):
C37H52NO3PPdS
分子量:
728.27
MDL编号:
UNSPSC代码:
12352101
NACRES:
NA.82

表单

solid

质量水平

组成

~ 4 wt.% loading of catalyst

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

SMILES字符串

[Pd+2].P(C76CC8CC(C7)CC(C6)C8)(C43CC5CC(C4)CC(C3)C5)CCCC.[S](=O)(=O)([O-])C.Nc1c(cccc1)c2[c-]cccc2

InChI key

QFHMWCPYABRFMY-UHFFFAOYSA-M

相关类别

应用

cataCXium® A Pd G3 is a Buchwald third generation precatalyst that can be used in:

  • Direct ortho-arylation of pyridinecarboxylic acids.
  • Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
  • Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
  • Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (761435)

法律信息

cataCXium is a registered trademark of Umicore AG & Co. KG

象形图

Health hazard

警示用语:

Danger

危险声明

危险分类

Carc. 1B Inhalation

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3


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分析证书(COA)

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商品

ChemBeads, catalyst-coated glass beads, dispense solid chemical reagents for nanomole-scale high-throughput reaction screening.

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