质量水平
检测方案
95%
形式
solid
特点
generation 3
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
杂质
≤3% acetone
mp
196-241 °C (decomposition)
官能团
phosphine
SMILES字符串
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
InChI
1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
InChI key
REYVZCOGMIXVNX-DVBMAMJVSA-M
应用
- 吡啶羧酸的直接邻位芳基化。
- 催化Suzuki–Miyaura交叉偶联反应,以合成1-杂芳基-3-氮杂双环[3.1.0]己烷。
- 炔烃的钯催化羰基碳全氟烷基化。
- 各种 gem二取代环丙烷的合成过程中成对二(溴基)环丙烷的Suzuki–Miyaura 偶联反应。
- 末端炔烃的溴全氟烷基化。
- 芳香卤化物和炔烃的无铜Sonogashira 偶联反应,以形成 C-C键。
- 有机三氟硼酸盐和芳基卤化物的Suzuki 交叉偶联反应。
法律信息
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
商品
All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form.
Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.
Materials Included in your KITALYSIS-24PD-2PK High-Throughput Screening Kit
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
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