761435
cataCXium® A Pd G3
95%
Synonym(s):
Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
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About This Item
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Quality Level
Assay
95%
form
solid
feature
generation 3
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
greener alternative product score
old score: 16
new score: 2
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greener alternative product characteristics
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impurities
≤3% acetone
mp
196-241 °C (decomposition)
1 of 4
This Item | 761311 | 761605 | 931055 |
|---|---|---|---|
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reaction type: Negishi Coupling, reagent type: catalyst | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst | reaction suitability - |
| mp 196-241 °C (decomposition) | mp 220 °C (decomposition) | mp 150-193 °C (decomposition) | mp - |
| form solid | form solid | form solid | form solid |
| feature generation 3 | feature generation 2 | feature generation 3 | feature - |
General description
Application
- Direct ortho-arylation of pyridinecarboxylic acids.[1][2]
- Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.[3]
- Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.[4]
- Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.[5]
- Boroperfluoroalkylation of terminal alkynes.[6]
- Copper-free Sonogashira coupling reaction of aromatic halides with alkynes to form C-C bond.[7]
- Suzuki cross-coupling between organotrifluoroborate and aryl halides.[8]
Legal Information
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form.
Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.
Materials Included in your KITALYSIS-24PD-2PK High-Throughput Screening Kit
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
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