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Merck
CN

902993

Sigma-Aldrich

(BPhen)Ni(OAc)2.xH2O

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About This Item

经验公式(希尔记法):
C28H22N2NiO4
分子量:
509.18
UNSPSC代码:
12161600
NACRES:
NA.22

检测方案

≥95%

形式

powder or crystals

反应适用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

SMILES字符串

O=C(O[Ni]OC(C)=O)C.C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5

应用

Catalyst for cross couplings via C-N bond activation

注意

Store under N2 atmosphere

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Corey H Basch et al.
Journal of the American Chemical Society, 139(15), 5313-5316 (2017-04-01)
We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki-Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C-N bond activation

商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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