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Merck
CN

902985

Sigma-Aldrich

(Bathocuproine)NiBr2

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经验公式(希尔记法):
C26H20Br2N2Ni
分子量:
578.95
UNSPSC代码:
12352300
NACRES:
NA.22

形式

powder or crystals

反应适用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

SMILES字符串

CC1=NC2=C(C=CC(C(C3=CC=CC=C3)=C4)=C2N=C4C)C(C5=CC=CC=C5)=C1.Br[Ni](C)(C)Br

应用

Catalyst for C-alkylation of nitroalkanes with unactivated alkyl iodides

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Sina Rezazadeh et al.
Journal of the American Chemical Society, 139(24), 8110-8113 (2017-06-09)
Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows

商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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