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CN
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安全信息

911844

Sigma-Aldrich

(Me4Phen)NiCl2

别名:

3,4,7,8-Tetramethyl-1,10-phenanthroline nickel (II) dichloride

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About This Item

经验公式（希尔记法）:
C16H16Cl2N2Ni
CAS号:
2254430-88-9
分子量:
365.91
UNSPSC代码:
12352200

表单

powder

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

mp

231 °C (decomp.)

应用

(Me4Phen)NiCl2 is a Ni catalyst used for a variety of cross-coupling reactions including the cross-electrophile coupling of benzyl alcohols and aryl halides.

其他说明

Nickel-Catalyzed Cross-Electrophile Coupling between Benzyl Alcohols and Aryl Halides Assisted by Titanium Co-reductant

警示用语：

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - STOT RE 1

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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Takuya Suga et al.
Organic letters, 20(24), 7846-7850 (2018-12-12)
A nickel-catalyzed cross-electrophile coupling reaction between benzyl alcohols and aryl halides has been developed using a homolytic C-O bond cleavage protocol that has recently been established. The treatment of a benzyl alcohol and aryl halide with a nickel catalyst and

商品

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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