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Merck
CN

911984

Sigma-Aldrich

(2,2′-Bipyridine)diiodonickel(II)

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别名:
(bpy)NiI2
经验公式(希尔记法):
C10H8I2N2Ni
CAS号:
分子量:
468.69
UNSPSC代码:
12352101
NACRES:
NA.22

形式

powder or crystals

反应适用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

应用

(2,2′-Bipyridine)diiodonickel(II) is a catalyst for the cross-electrophile coupling of vinyl halides and alkyl halides.

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Muta. 2 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Kirk W Shimkin et al.
Journal of the American Chemical Society, 140(23), 7074-7078 (2018-05-26)
Nickel-catalyzed cross-electrophile couplings have recently emerged as highly effective and practical methods for the formation of C-C bonds. By merging this process with well-established π-π coupling chemistry, a new method for the synthesis of tetrasubstituted alkenes has been developed. The

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