检测方案
99%
形式
solid
mp
52-55 °C (lit.)
SMILES字符串
[O-][N+](=O)c1ccc(OS(=O)(=O)C(F)(F)F)cc1
InChI
1S/C7H4F3NO5S/c8-7(9,10)17(14,15)16-6-3-1-5(2-4-6)11(12)13/h1-4H
InChI key
NDTIXHNCNLKURN-UHFFFAOYSA-N
应用
4-Nitrophenyl trifluoromethanesulfonate (4-nitrophenyltriflate) may be used in the following studies:
- As a triflating agent in the synthesis of aryl triflates.
- As a reagent in the synthesis of aryl nonaflate.
- As a reagent for palladium catalyzed coupling reactions with different substrates.
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
4-Nitrophenyltriflate as a new triflating agent.
Zhu J, et al.
Tetrahedron Letters, 38(7), 1181-1182 (1997)
A high throughput synthesis of aryl triflate and aryl nonaflate promoted by a polymer supported base (PTBD).
Boisnard S, et al.
Tetrahedron Letters, 40(42), 7469-7472 (1999)
Palladium-catalyzed cross-coupling reaction of organoboron compounds with organic triflates.
Ohe T, et al.
The Journal of Organic Chemistry, 58(8), 2201-2208 (1993)
Regioselective palladium-catalyzed arylation of vinyl ethers with 4-nitrophenyl triflate. Control by addition of halide ions.
Andersson CM and Hallberg A.
The Journal of Organic Chemistry, 53(9), 2112-2114 (1988)
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