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文件

677922

Sigma-Aldrich

[双(三氟甲烷磺酰)亚胺](三苯基膦)金(I)(2:1)甲苯加合物

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别名:
[双(三氟甲烷磺酰)亚胺](PPh3)金(I)(2:1)甲苯加合物
线性分子式:
(C20H15AuF6NO4PS2) 2 · C7H8
分子量:
1570.93
MDL编号:
MFCD09038445
UNSPSC代码:
12352300
PubChem化学物质编号:
24885406
NACRES:
NA.22

形式

solid

质量水平

100

反应适用性

core: gold
reagent type: catalyst

SMILES字符串

[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1

InChI key

SIVCTOVPPFSWEF-UHFFFAOYSA-N

相关类别

应用

金催化剂— 21世纪 ′淘金热′
[双(三氟甲磺酰基)亚胺酯](三苯基膦)金(I)（2:1）甲苯加合物可作为通过Meyer-Schuster重排反应将炔丙醇1,3-异构化为烯酮的催化剂。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

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