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Merck
CN

258105

硫酸

ACS reagent, 95.0-98.0%

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线性分子式:
H2SO4
化学文摘社编号:
分子量:
98.08
UNSPSC Code:
12352106
NACRES:
NA.21
PubChem Substance ID:
EC Number:
231-639-5
Beilstein/REAXYS Number:
2037554
MDL number:
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产品名称

硫酸, ACS reagent, 95.0-98.0%

form

liquid

assay

95.0-98.0%

InChI

1S/H2O4S/c1-5(2,3)4/h(H2,1,2,3,4)

InChI key

QAOWNCQODCNURD-UHFFFAOYSA-N

SMILES string

OS(O)(=O)=O

grade

ACS reagent

agency

suitable for EPA 1613
suitable for SM 4500 - NH3
suitable for SM 5210

vapor density

<0.3 (25 °C, vs air)

vapor pressure

1 mmHg ( 146 °C)

description

Free from suspended or insoluble matter
Nominally 95-98% H2SO4

ign. residue

≤5 ppm

color

APHA: ≤10

pH

1.2 (5 g/L)

bp

~290 °C (lit.)

Quality Level

solubility

water: soluble

density

1.840 g/mL at 25 °C (lit.)

anion traces

MnO4- reducers: ≤2 ppm
chloride (Cl-): ≤0.2 ppm
nitrate (NO3-): ≤0.5 ppm

cation traces

As: ≤0.01 ppm
Fe: ≤0.2 ppm
Hg: ≤5 ppb
NH4+: ≤2 ppm
heavy metals: ≤1 ppm (by ICP)

application(s)

PFAS testing

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Application

硫酸可作为催化剂:
  • 用于仲硝基烷烃盐到醛或酮的水解。
  • 腈到酰胺的选择性水解。
  • 通过丁腈与烯烃的 Ritter 反应合成叔烷基碳胺酰胺。
  • 通过 α,β-不饱和醛的羰基化制备 3,4-二烷基-2(5H)-呋喃酮。
  • 芳香碳环和杂芳香化合物的硝化。
  • 以酸酐为原料经 α-氨基烷基化反应合成 Friedel–Craft 酮。

H2SO4 还可用于以下反应:
  • Michael 加成反应
  • 亲电取代反应
  • 高阻碍芳酸酯化反应
  • Aldol 缩合反应
  • Beckmann 重排
  • Hofmann–Loffler–Freytag 反应
  • 异构化
  • 脱氢
  • 磺化

Other Notes

4L和4X4L聚乙烯瓶封装
ACS规格与产品320501相同
带-PC的SKU包装规格采用PVC涂层玻璃瓶包装。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
易制毒化学品(3类)
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. What is the concentration of Sulfuric acid, Product 258105, in moles per liter (M)?

    This material has a calculated, theoretical concentration of 18 M.

  4. How was the concentration of Sulfuric acid, Product 258105, calculated?

    The molarity is calculated using the following equation:molarity=[(1000 X Density)/molecular weight] X (percent purity/100).

  5. How is Sulfuric acid, Product 258105, to be stored?

    This material is a room temperature storage item.

  6. What is the shelf life of Sulfuric acid, Product 258105?

    This material does not have an expiration or a recommended retest date established for it.  Rather, we guarantee it for one year upon the date of receipt.

  7. What is Sulfuric acid, Product 258105, dissolved in?

    This material is not dissolved in anything.  Rather it is pure sulfuric acid, which is a liquid at room temperature.

  8. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  9. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  10. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Tim Olding et al.
Physics in medicine and biology, 56(5), 1259-1279 (2011-02-03)
This work develops imaging protocols for improved dose readout of a Fricke-xylenol orange-gelatin (FXG) gel-filled 1 L polyethylene terephthalate (PETE) jar dosimeter using a commercial Vista(TM) cone-beam optical computed tomography (CT) scanner from Modus Medical Devices Inc. (London, ON, Canada).
Determination of mercury in natural waters and effluents by flameless atomic absorption spectrophotometry.
S H Omang
Analytica chimica acta, 53(2), 415-419 (1971-02-01)
Self-Ordering of Cell Arrangement of Anodic Porous Alumina Formed in Sulfuric Acid Solution.
Masuda H, et al.
Journal of the Electrochemical Society, 144(5), L127-L130 (1997)
Investigation of the kinetics and mechanism of the anodic oxidation of aniline in aqueous sulfuric acid solution at a platinum electrode.
Mohilner DM, et al.
Journal of the American Chemical Society, 84(19), 3618-3622 (1962)
Jing Li et al.
Journal of chromatography. A, 1404, 39-43 (2015-06-09)
The paper reports on a novel method for rapid determination of carbonyl in lignins by headspace gas chromatography (HS-GC). The method involves the quantitative carbonyl reduction for aldehydes in 2min at room temperature or for acetones in 30min at 80°C

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