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Merck
CN

35990

Supelco

2,3-二氯-1,4-萘醌

for spectrophotometric det. of hydrazides, ≥98.0%

别名:

二氯萘醌

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About This Item

经验公式(希尔记法):
C10H4Cl2O2
CAS号:
分子量:
227.04
Beilstein:
1073511
EC 号:
MDL编号:
UNSPSC代码:
41116105
PubChem化学物质编号:
NACRES:
NA.21

描述

algaecide

质量水平

方案

≥98.0% (AT)
≥98.0%

表单

powder

质量

for spectrophotometric det. of hydrazides

技术

UV/Vis spectroscopy: suitable

mp

192-195 °C
194-197 °C (lit.)

SMILES字符串

ClC1=C(Cl)C(=O)c2ccccc2C1=O

InChI

1S/C10H4Cl2O2/c11-7-8(12)10(14)6-4-2-1-3-5(6)9(7)13/h1-4H

InChI key

SVPKNMBRVBMTLB-UHFFFAOYSA-N

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一般描述

2,3-Dichloro-1,4-naphthoquinone is a potent and safe fungicide, and finds application in both agriculture and textile industry. During seed treatment, it is used as a foliage spray and is also an excellent mildew-proofing agent. Furthermore it also resists weathering.

应用

2,3-Dichloro-1,4-naphthoquinone was used in its alkaline form in the colorimetric method, used for the spectrophotometric determination of hydrazides. It may also be used for the spectrophotometric analysis of isoniazid in the presence of its hydrazones.

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

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分析证书(COA)

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2, 3-Dichloro-1, 4-naphthoquinone
Horst WP and Felix EL.
Ind. and Eng. Chem., 35 (12), 1255-1259 (1943)
Spectrophotometric determination of isoniazid in presence of its hydrazones.
Devani MB
Journal of Pharmaceutical Sciences, 67 (5), 661-663 (1978)
Spectrophotometric determination of hydrazides with 2, 3-dichloro-1, 4-napthoquinone.
Plaizier JA
Analytical Chemistry, 48 (11), 1536-1538 (1976)
Angupillai Satheshkumar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 98, 378-383 (2012-09-18)
Various spectroscopy techniques (UV-Vis, DRS, FT-IR, (1)H NMR, LC-MS) and theoretical computations have been employed to investigate the mechanism of the nucleophilic substitution reaction of 2,3-dichloronaphthoquinone (DCNQ) with para-substituted anilines in solid state under base- and solvent-free conditions against traditional
H J Kallmayer et al.
Die Pharmazie, 58(2), 104-107 (2003-03-19)
Isopropyl-alkylamines 2 react with 2,3-dichloro-1,4-naphthoquinone (1) to give red 2-chloro-3-isopropyl-alkylamino-1,4-naphthoquinones 3 and with 2,3-dichloro-1,4-naphthoquinone/acetaldehyde to give blue 2-chloro-3-isopropylalkylamino-vinyl-1,4-naphthoquinones 7. It is evident that the formation of 7 is preferred sterically to the formation of 3. The reaction between 2, 1

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