22880
氯乙酰氯
purum, ≥99.0% (GC)
别名:
Chloroacetic chloride
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线性分子式:
ClCH2COCl
化学文摘社编号:
分子量:
112.94
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-171-6
Beilstein/REAXYS Number:
605439
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid
InChI key
VGCXGMAHQTYDJK-UHFFFAOYSA-N
InChI
1S/C2H2Cl2O/c3-1-2(4)5/h1H2
SMILES string
ClCC(Cl)=O
vapor density
3.9 (vs air)
vapor pressure
60 mmHg ( 41.5 °C)
grade
purum
assay
≥99.0% (GC)
form
liquid
Quality Level
bp
105-106 °C (lit.)
mp
−22 °C (lit.)
solubility
water: insoluble
density
1.419 g/mL at 20 °C, 1.418 g/mL at 25 °C (lit.)
functional group
acyl chloride, chloro
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General description
氯乙酰氯是一种脂肪族酰氯。
Application
氯乙酰氯可用于制备：
- 通过吡啶-2-胺的N-酰化作用制备2-氯-N-(吡啶-2-基)乙酰胺
- 通过 N,N-二甲基甲酰胺与纤维素反应，制备氯乙酰纤维素
- 在回流甲苯中存在碱的条件下，通过与1,3-苯并噻嗪反应制备苯并噻嗪类衍生物
- 通过与3,5-二芳基-4,5-二氢吡唑反应制备2-氯-1-(3,5-二芳基-4,5-二氢吡唑-1-基)-乙酮
- 在微波条件下，通过与氯代靛红反应，制备氯乙酰基
氯乙酰氯用于合成 N-肼基乙酰磺酰胺。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1
target_organs
Lungs
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
212.0 °F - closed cup
flash_point_c
100 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
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