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表单
liquid
质量水平
浓度
1.0 M in THF
密度
0.891 g/mL at 25 °C
SMILES字符串
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
YNESATAKKCNGOF-UHFFFAOYSA-N
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一般描述
三甲基硅基胺基锂(LHMDS)是一种非亲核强碱,广泛应用于有机合成中的脱保护反应和碱催化反应。它通常可溶于大多数非极性有机溶剂。
应用
双三甲基硅基胺基锂溶液(1.0 M,溶于THF溶液)可用作碱:
- 催化聚(对苯甲酰胺)合成中的聚合反应。
- 用于环状聚(α-类肽)和α-(二氟甲基)苯乙烯的合成。
- 用于定向醛醇缩合和Darzens缩合反应;芳基酯衍生物的α-芳基化和烯丙基胺化反应。
- 与六甲基二硅基氮烷钠(NaHMDS)相比,可用于生成动力学烯醇化物(kinetic enolate),因为生成的烯醇化物比NaHMDS生成的烯醇化物更具有区域稳定性(regiostable )。
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险分类
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system, Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
1.4 °F - closed cup
闪点(°C)
-17 °C - closed cup
法规信息
危险化学品
? -(Difluoromethyl) styrene: improved approach to grams scale synthesis
Journal of Fluorine Chemistry, 179, 175-178 (2015)
Macromolecules, 39, 5347-5347 (2006)
Dental materials : official publication of the Academy of Dental Materials, 25(6), 729-735 (2009-01-29)
The objectives of this study were to assess demineralized dentin porosity and quantify the different porous features distribution within the material using mercury intrusion porosimetry (MIP) technique. We compared hexamethyldisilazane (HMDS) drying and lyophilization (LYO) (freeze-drying) in sample preparation. Fifty-six
Journal of microbiological methods, 90(2), 96-99 (2012-05-09)
The use of hexamethyldisilazane (HMDS) as a drying agent was investigated in the specimen preparation for scanning electron microscopy (SEM) imaging of bacterial surface colonization on sub-bituminous coal. The ability of microbes to biofragment, ferment and generate methane from coal
Chemical communications (Cambridge, England), 47(38), 10761-10763 (2011-08-30)
A silica microsphere suspension and a silica sol are employed in a two-step dipping process for the preparation of a superhydrophobic surface. It's not only a facile way to achieve the lotus effect, but can also create a multi-functional surface
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