形式
powder
质量水平
反应适用性
reagent type: catalyst
reaction type: C-H Activation
reagent type: surfactant
环保替代产品特性
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
转变温度
Tm 29-34
环保替代产品分类
, Aligned
一般描述
应用
TPGS-750-M也可用于:
- 芳基和杂芳基卤化物与氮、氧、硫亲核试剂在温和条件下的亲核芳香取代反应。
- 喹喔啉酮经C(sp2)羟化反应制取喹喔啉-2,3二酮。
- 使用铜催化剂的胺的分子内N-芳基化。
其他说明
从毫克到公斤:遵循自然引导的合成化学′
闪点(°F)
Not applicable
闪点(°C)
Not applicable
商品
Lipshutz及其同事最近开发了第二代技术,用于基于聚氧乙戊基-α-生育酚琥珀酸酯衍生物TPGS-750-M的原始PTS表面活性剂。
Micellular catalysis has provided the ability to carry out several commonly used transformations used in the synthetic community to be carried out in water.
Lipshutz and co-workers have recently developed a second generation technology to their original PTS-enabling surfactant based on the polyoxyethanyl-α-tocopheryl succinate derivative, TPGS-750-M.
Surfactants for efficient reactions in water as a green chemistry alternative.
实验方案
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
相关内容
Prof. Bruce Lipshutz and co-workers have developed designer surfactants to allow several classes of transformations (e.g. Suzuki-Miyaura, Olefin Metathesis, 1,4-Addition to Enones, etc.) to be performed in water.
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