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726842

(R)-(+)-4-甲氧基-α-甲基苄胺

Name: (<I>R</I>)-(+)-4-甲氧基-α-甲基苄胺
Brand: ALDRICH

ChiPros^®, produced by BASF, 99%

别名:

(R)-(+)-1-(4-甲氧基苯基)乙胺

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About This Item

经验公式（希尔记法）:

C₉H₁₃NO

CAS号:

22038-86-4

分子量:

151.21

Beilstein:

2413029

MDL编号:

MFCD00671659

UNSPSC代码:

12352112

PubChem化学物质编号:

329764270

NACRES:

NA.22

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95889

(S)-(-)-4-甲氧基-α-甲基苄胺

Sigma-Aldrich

410896

2-羟基-4′-(2-羟乙氧基)-2-甲基苯丙酮

Sigma-Aldrich

723193

季戊四醇四(2-溴异丁酸酯)

Sigma-Aldrich

726656

(S)-(-)-4-甲氧基-α-甲基苄胺

Sigma-Aldrich

763551

Pentaerythritol tetrakis[2-(dodecylthiocarbonothioylthio)-2-methylpropionate]

Sigma-Aldrich

115541

(R)-(+)-α-甲基苄胺

Sigma-Aldrich

763071

3,5-双（2-十二烷基硫代羰基硫代硫基硫代-1-氧代丙氧基）苯甲酸

Sigma-Aldrich

115568

(S)-(-)-α-甲基苄胺

Sigma-Aldrich

461385

(R)-(+)-β-甲基苯乙胺

Sigma-Aldrich

381462

季戊四醇四-3-巯基丙酸酯

等级

produced by BASF

质量水平

100

方案

≥98.5% (GC)
99%

表单

liquid

光学纯度

enantiomeric excess: ≥98.5%

密度

1.024 g/mL at 20 °C (lit.)

官能团

amine

SMILES字符串

COc1ccc(cc1)[C@@H](C)N

InChI

1S/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/m1/s1

InChI key

JTDGKQNNPKXKII-SSDOTTSWSA-N

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应用

(R)-(+)-4-Methoxy-α-methylbenzylamine can be used as a reactant to prepare:

Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N′-methylthiourea by reacting with methyl isothiocyanate.

法律信息

ChiPros is a registered trademark of BASF SE

象形图

GHS05,GHS07

警示用语：

Danger

危险声明

H302,H314,H317,H412

预防措施声明

P261 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1A

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of (+)-and (-)-Geissman-Waiss lactone from chiral sulfonium salts

Lopez-Gonzalez R, et al.

Tetrahedron Letters, 12(24), 151697-151697 (2020)

Improved hemicryptophane hosts for the stereoselective recognition of glucopyranosides

Schmitt A, et al.

Organic & Biomolecular Chemistry, 12(24), 4211-4217 (2014)

N-methylthioureas as new agonists of retinoic acid receptor-related orphan receptor.

Yohan Park et al.

Archives of pharmacal research, 35(8), 1393-1401 (2012-09-04)

Thirty two thiourea derivatives were prepared and their agonistic activities on the retinoic acid receptor-related orphan receptor α (RORα) were evaluated. The replacement of the 3-allyl-2-imino-thiazolidin-4-one moiety of the lead compound CGP52608 (1) with various functional group substituted aromatic rings

商品

ChiPros Chiral Amines

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

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(R)-(+)-4-甲氧基-α-甲基苄胺