所有图片(1)
About This Item
经验公式（希尔记法）:
C39H62O6S6
分子量:
819.30
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.23
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方案
98% (HPLC)
表单
powder or crystals
mp
60-65 °C
储存温度
2-8°C
SMILES字符串
CCCCCCCCCCCCSC(=S)SC(C)C(=O)Oc1cc(OC(=O)C(C)SC(=S)SCCCCCCCCCCCC)cc(c1)C(O)=O
InChI
1S/C39H62O6S6/c1-5-7-9-11-13-15-17-19-21-23-25-48-38(46)50-30(3)36(42)44-33-27-32(35(40)41)28-34(29-33)45-37(43)31(4)51-39(47)49-26-24-22-20-18-16-14-12-10-8-6-2/h27-31H,5-26H2,1-4H3,(H,40,41)
InChI key
GOLRGLNMILBFFI-UHFFFAOYSA-N
一般描述
Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.
Reversible addition-fragmentation chain transfer (RAFT) polymerization is used to produce narrow polydispersity polymers of complex architecture. 3,5-Bis(2-dodecylthiocarbonothioylthio-1-oxopropoxy)benzoic acid is a carboxylic acid functionalised trithiocarbonate RAFT agent. It is used to form well-defined block copolymers. They have good control of polymerisation for a wide range of vinyl monomers.
应用
Used in the synthesis of macro-Chain Transfer Agent (CTA) which are used in the RAFT polymerisation of vinylic monomers like styrene, acrylate and acrylamide.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
历史批次信息供参考:
Block copolymers of poly (2-oxazoline) s and poly (meth) acrylates: a crossover between cationic ring-opening polymerization (CROP) and reversible addition-fragmentation chain transfer (RAFT).
Krieg, A., Weber, C., Hoogenboom, R., Becer, C. R., & Schubert, U. S.
ACS Macro Letters, 1(6), 776-779 (2012)
Thiocarbonylthio compounds (SC (Z) SR) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization).
Chiefari, J., Mayadunne, R. T., Moad, C. L., Moad, G., Rizzardo, E., Postma, A., & Thang, S. H.
Macromolecules, 36(7), 2273-2283 (2003)
One-step synthesis of block copolymers using a hydroxyl-functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H.
Journal of Polymer Science Part A: Polymer Chemistry, 51(4), 774-779 (2013)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being
商品
The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.
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