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Merck
CN

115541

Sigma-Aldrich

(R)-(+)-α-甲基苄胺

98%

别名:

(R)-(+)-1-苯乙胺

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About This Item

线性分子式:
C6H5CH(CH3)NH2
CAS号:
分子量:
121.18
Beilstein:
2410916
EC 号:
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

0.5 mmHg ( 20 °C)

质量水平

检测方案

98%

旋光性

[α]23/D +38°, neat

光学纯度

ee: 96% (GLC)

折射率

n20/D 1.526 (lit.)

bp

187-189 °C (lit.)

密度

0.952 g/mL at 20 °C (lit.)

储存温度

2-8°C

SMILES字符串

C[C@@H](N)c1ccccc1

InChI

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m1/s1

InChI key

RQEUFEKYXDPUSK-SSDOTTSWSA-N

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应用

(R)-(+)-α-甲基苄胺是一种手性胺,可用作合成(S)-α-氨基膦酸酯、 R-α-氨基腈、 N-{(S)-[环己烷-(S)-2-醇]}-(R)-α-甲基苄胺和 N-{(R)-[环己烷-(R)-2-醇]}-(R)-α-甲基苄胺的底物。当存在硼酸时,它可用于拆分消旋1,1′-二-2-萘酚。

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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A New, Convenient Method of Resolution of Racemic 1, 1 '-Bi-2-naphthol Using Boric Acid and (R)-(+)-a-Methylbenzylamine
Periasamy M, et al
The Journal of Organic Chemistry, 64(20), 7643-7645 (1999)
Lithium perchlorate/diethylether catalyzed aminophosphonation of aldehydes.
Heydari A, et al.
Tetrahedron Letters, 39(37), 6729-6732 (1998)
Lithium perchlorate/diethylether catalyzed aminocyanation of aldehydes
Heydari A, et al
Tetrahedron Letters, 39(19), 3049-3050 (1998)
New enantiomerically pure aminoalcohols from (R)-a-methylbenzylamine and cyclohexene oxide.
Barbaro P, et al.
Tetrahedron Asymmetry, 7(3), 843-850 (1996)
Lili Men et al.
Cellular physiology and biochemistry : international journal of experimental cellular physiology, biochemistry, and pharmacology, 51(5), 2185-2197 (2018-12-12)
VCP-interacting membrane selenoprotein (VIMP), an ER resident selenoprotein, is highly expressed in β-cells, however, the role of VIMP in β-cells has not been characterized. In this study, we studied the relationship between VIMP deficiency and β-cell survival in MIN6 insulinoma

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