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Merck
CN

701602

[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II)

greener alternative

98%, powder

别名:

1,1′-Bis-(di-tert.-butylphosphino-)ferrocen-palladiumdichlorid, PdCl2(dtbpf)

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关于此项目

经验公式（希尔记法）:
C26H44Cl2FeP2Pd
化学文摘社编号:
95408-45-0
分子量:
651.75
UNSPSC Code:
12161600
PubChem Substance ID:
329762308
NACRES:
NA.22
MDL number:
MFCD08064219

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产品名称

[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II), 98%

SMILES string

[Fe].Cl[Pd]Cl.CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C

InChI

1S/2C13H22P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*7-10H,1-6H3;2*1H;;/q;;;;;+2/p-2

InChI key

JQZFOBWXNREQLO-UHFFFAOYSA-L

assay

98%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

203-208 °C

greener alternative category

, Aligned

storage temp.

−20°C

Quality Level

200

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Application

钯催化交叉偶联反应应用指南
[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II) 被用于制备[PdCl2（二膦基金属茂）]配合物。据报道，这些配合物是Buchwald-Hartwig反应的催化剂前体。
它也被用于催化TPGS-750-M中发生的环保型Suzuki交叉偶联反应。

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II)（PdCl2(dtbpf)）可催化各种芳族和杂芳族卤化物与甲基亚氨基二乙酸衍生物（MIDA硼酸酯）在室温下（在不含有机溶剂的条件下）的Suzuki交叉偶联反应。它可以催化查耳酮合成过程中的交叉偶联反应。

General description

[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II) （PdCl2(dtbpf)）可催化Suzuki和Heck反应。这种预催化剂是由Johnson Matthey′s Catalysis and Chiral Technologies公司的一组研究人员合成的。它是各种Pd催化交叉偶联反应的活性催化剂。
[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II) 是一种空气稳定的、高活性和多功能的催化剂。它是交叉偶联反应的有效催化剂。它能催化精细化学品和药物化学品的各种偶联反应。在Suzuki反应中常用作均相催化剂。

PdCl2(dtbpf)是一种空气稳定的交叉偶联催化剂，用于各种芳氯化物的Suzuki偶联。
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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB0983
STBK9193
STBK5590
STBK3920
STBK2659

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An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides.
Bumagin NA, et al.
Chemistry of Heterocyclic Compounds, 50(1), 19-25 (2011)
?-Arylation of ketones using highly active, air-stable (DtBPF) PdX2 (X= Cl, Br) catalysts
Grasa GA and Colacot TJ
Organic Letters, 9(26), 5489-5492 (2007)
Bruce H Lipshutz et al.
Organic letters, 10(7), 1329-1332 (2008-03-14)
A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross-couplings of non-water-soluble partners at ambient temperatures. These are the first examples of Heck reactions conducted in water (as
Gabriela A Grasa et al.
Organic letters, 9(26), 5489-5492 (2007-11-23)
alpha-Arylation of various ketones with aryl chlorides and bromides using the well-defined and air-stable (DtBPF)PdX2 (X = Cl, Br) catalysts gave 80-100% yield of the coupled products under relatively mild conditions at low catalyst loadings. The X-ray structure of (DtBPF)PdCl2
CRC International Symposium: Cross Coupling and Organometallics.
Colacot T.
Platinum Metals Rev., 52(3), 172-172 (2008)
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实验方案

Cross-Coupling Reactions in Water

TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.

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