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Merck
CN

679208

Sigma-Aldrich

甲基三氯硅烷

deposition grade, ≥98% (GC), ≥99.99% (as metals)

别名:

三氯(甲基)硅烷

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About This Item

线性分子式:
CH3SiCl3
CAS号:
分子量:
149.48
Beilstein:
1361381
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

等级

deposition grade

质量水平

蒸汽密度

5.2 (vs air)

蒸汽压

150 mmHg ( 25 °C)

检测方案

≥98% (GC)
≥99.99% (as metals)

形式

liquid

自燃温度

>760 °F

expl. lim.

11.9 %

折射率

n20/D 1.411 (lit.)

bp

66 °C (lit.)

密度

1.273 g/mL at 25 °C (lit.)

SMILES字符串

C[Si](Cl)(Cl)Cl

InChI

1S/CH3Cl3Si/c1-5(2,3)4/h1H3

InChI key

JLUFWMXJHAVVNN-UHFFFAOYSA-N

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警示用语:

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

靶器官

Respiratory system

WGK

WGK 1

闪点(°F)

closed cup

闪点(°C)

closed cup

法规信息

危险化学品

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Yingbin Ge et al.
The journal of physical chemistry. A, 114(6), 2384-2392 (2010-01-29)
The rate constants for the gas-phase reactions in the silicon carbide chemical vapor deposition of methyltrichlorosilane (Ge, Y. B.; Gordon, M. S.; Battaglia, F.; Fox, R. O. J. Phys. Chem. A 2007, 111, 1462.) were calculated. Transition state theory was
Ana Gisela Cunha et al.
Journal of colloid and interface science, 344(2), 588-595 (2010-02-05)
This work describes a very simple, rapid, and efficient approach to the hydrophobization and lipophobization of cellulose fibers through their reaction with gaseous trichloromethylsilane (TCMS). The characterization of the modified surface involved FTIR-ATR and solid-state (29)Si NMR spectroscopy, scanning electron
W H Mullen et al.
Clinica chimica acta; international journal of clinical chemistry, 157(2), 191-198 (1986-06-15)
An enzyme electrode is described based upon the enzyme lactate oxidase (EC 1.1.3.2) coupled to an H2O2 sensor. Use of an organosilane-treated microporous membrane over the enzyme layer, allows responses linear to 18 mmol/l L-lactate with response times of 1-3
Yingbin Ge et al.
The journal of physical chemistry. A, 111(8), 1475-1486 (2007-02-06)
The kinetics for the previously proposed 114-reaction mechanism for the chemical vapor deposition (CVD) process that leads from methyltrichlorosilane (MTS) to silicon carbide (SiC) are examined. Among the 114 reactions, 41 are predicted to proceed with no intervening barrier. For
Ildikó Szabó et al.
Biopolymers, 88(1), 20-28 (2006-10-26)
Rearrangement of disulfide bonds during the synthesis of alpha-conotoxin GI using PhS(O)Ph/CH(3)SiCl(3) oxidation procedure was observed. We have demonstrated that the protecting scheme (order of acetamidomethyl (Acm) and (t)Bu protecting groups) of the Cys residues as well as the reaction

商品

Deposition Grade Silanes, fully characterized by chemical analysis and nuclear magnetic resonance (NMR) with greater than 98% purity, for Sol-Gel Processes.

涉及到反应性有机硅化学的研究已聚焦于纯硅和杂合材料的生产、氢化硅烷化、开环和原子转移聚合,以及具有受控立体化学的聚合和缩合反应。

Reactive silicone chemistry: Focus on pure silicon production, polymerizations, and controlled stereochemistry reactions.

atomic layer deposition (ALD), microelectronics, Mo:Al2O3 films, nanocomposite coating, photovoltaics, semiconductor devices, W:Al2O3 films, composite films, layer-by-layer

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