所有图片(1)
About This Item
线性分子式:
C5H4PC6H5C5H4Fe
CAS号:
分子量:
292.09
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
88-92 °C (lit.)
官能团
phosphine
储存温度
2-8°C
SMILES字符串
[Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
InChI
1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChI key
HKOUDNXXOXEYNZ-UHFFFAOYSA-N
应用
Reactant for:
- Preparation of macrocyclic tridentate ferrocenylphosphine ligands
- Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
- Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
- Ring-opening reactions via ring slippage
- Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
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