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方案
96%
沸点
110-112 °C/30 mmHg (lit.)
mp
25 °C (lit.)
密度
1.473 g/mL at 25 °C (lit.)
官能团
amine
bromo
SMILES字符串
NCc1ccc(Br)cc1
InChI
1S/C7H8BrN/c8-7-3-1-6(5-9)2-4-7/h1-4H,5,9H2
InChI key
XRNVSPDQTPVECU-UHFFFAOYSA-N
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一般描述
4-溴苄胺（BBA）又名 p-溴苄胺，是一种芳基溴化物。据报道，在存在红铜的条件下，其可由BBA选择性地形成腈或亚胺。 BBA形成2,6,9-三氮杂双环[3.3.1]壬烷衍生物的formal[4 + 4]反应已有研究。
应用
4-溴苄胺(p-溴苄胺)可用于合成7-[(p-溴苄基)脲基]-7,8-二氢-α-双丁二烯。
它可用于合成以下4-联苯甲胺衍生物：
它可用于合成以下4-联苯甲胺衍生物：
- (4′-氟-4-联苯)甲胺
- (4′-甲氧基-4-联苯)甲胺
- (2′-甲氧基-4-联苯)甲胺
- (3′-氰基-4-联苯)甲胺
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
>230.0 °F - closed cup
闪点(°C)
> 110 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Jiaqing Wang et al.
Chemical communications (Cambridge, England), 50(42), 5637-5640 (2014-04-16)
A novel, efficient, convenient and environmentally friendly approach for the synthesis of nitriles and imines from primary amines has been developed. Using commercially available red copper as the catalyst, ammonium bromide as the co-catalyst and molecular oxygen as the sole
Jing Zhuang et al.
Nanoscale, 11(31), 14553-14560 (2019-07-26)
An all-inorganic CsPbI2Br perovskite with excellent phase stability and thermal stability has been considered to be a promising candidate for photovoltaic application. However, low efficiency and high moisture sensitivity hinder its advancement. In this work, we exploit 4-bromobenzylamine hydriodate post-treatment
Silvia Galiano et al.
Bioorganic & medicinal chemistry, 15(11), 3896-3911 (2007-04-05)
We have designed and synthesized two novel series of MCH-R1 antagonists based on a substituted biphenylmethyl urea core. SAR was explored, suggesting that optimal binding with the receptor was achieved when the biphenylmethyl group and the linker were substituted on
Efficient synthesis of 2,6,9-triazabicyclo [3.3.1] nonanes through amine-mediated formal [4+4] reaction of unsaturated imines.
Tanaka K, et al.
Tetrahedron Letters, 53(44), 5899-5902 (2012)
Nitrogenous bisabolene sesquiterpenes from marine invertebrates.
Gulavita NK, et al.
The Journal of Organic Chemistry, 51(26), 5136-5139 (1986)
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