所有图片(2)
别名:
(4-Methoxyphenyl)methanamine, (p-Methoxyphenyl)methanamine, 1-Aminomethyl-4-methoxybenzene, 4-Methoxybenzenemethanamine, Anisylamine, p-Methoxybenzylamine
线性分子式:
CH3OC6H4CH2NH2
CAS号:
分子量:
137.18
Beilstein:
508206
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
检测方案
98%
形式
liquid
折射率
n20/D 1.546 (lit.)
bp
236-237 °C (lit.)
密度
1.05 g/mL at 25 °C (lit.)
SMILES字符串
COc1ccc(CN)cc1
InChI
1S/C8H11NO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6,9H2,1H3
InChI key
IDPURXSQCKYKIJ-UHFFFAOYSA-N
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应用
4-甲氧基苄胺属于一级胺，可用于：
- 官能化芳基溴的胺化反应。
- 合成体内应用的官能化有机聚磷腈。
- 合成具有抗增殖活性的肌球蛋白、8-氮杂嘌呤类似物。
- 研究2-硝基-和2,4-二硝基苯磺酰胺等氨基保护基团的脱保护步骤。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
T Jonsson et al.
Biochemistry, 33(49), 14871-14878 (1994-12-13)
Competitive kH/kT and kD/kT kinetic isotope effects on p-methoxybenzylamine oxidation by the 8 alpha-S-cysteinyl flavin adenine dinucleotide (FAD)-dependent enzyme monoamine oxidase B (MAO-B) have been measured as a function of temperature. At pH 7.5, exponents relating observed kH/kT and kD/kT
2-Nitro-and 2, 4-dinitrobenzenesulfonamides as protecting groups for primary amines.
Nihei KI, et al.
Synlett, 2001(07), 1167-1169 (2001)
Synthesis and biological activity of 8-azapurine and pyrazolo [4, 3-d] pyrimidine analogues of myoseverin.
Krystof V, et al.
European Journal of Medicinal Chemistry, 41(12), 1405-1411 (2006)
Anna Berlicka et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 9(10), 1359-1366 (2010-09-08)
A variety of primary and secondary benzylic amines were oxidized efficiently to N-benzylidenebenzylamines and imines, respectively, using 2,7,12,17-tetrapropylporphycene (H(2)TPrPc) photocatalyst and blue light emitting diodes (LEDs). The photooxidation of 4-methoxybenzylamine in the presence of H(2)TPrPc and its tin(IV) complex Sn(TPrPc)Cl(2)
Mild and efficient copper-catalyzed amination of aryl bromides with primary alkylamines.
Kwong FY and Buchwald SL
Organic Letters, 5(6), 793-796 (2003)
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