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Merck
CN

363359

Sigma-Aldrich

2-丁烯,顺式和反式混合物

≥99%

别名:

β-Butylene, Pseudobutylene

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About This Item

线性分子式:
CH3CH=CHCH3
CAS号:
分子量:
56.11
Beilstein:
1718755
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽压

1.9 mmHg ( 0 °C)

质量水平

方案

≥99%

expl. lim.

9.3 %

沸点

1 °C (lit.)

mp

−140 °C (lit.)

SMILES字符串

C\C=C\C

InChI

1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+

InChI key

IAQRGUVFOMOMEM-ONEGZZNKSA-N

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一般描述

2-Butene is an alkene. All-silica zeolite RUB-41, containing 8- and 10-membered rings, is reported to be capable of separating trans-2-butene and cis-2-butene from 1-butene. Asymmetric gydrozirconation of cis- and trans-2-butene is reported. Stereospecific addition of methylene to trans-2-butene is reported to afford trans-1,2dimethylcyclopropane while similar addition to cis-2-butene affords cis-1,2dimethylcyclopropane.

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推荐使用铜质软管接头 Z146811 或铜体微型气流阀 Z513539。

调节阀

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说明
价格

软管倒钩

产品编号
说明
价格

象形图

FlameGas cylinder

警示用语:

Danger

危险声明

预防措施声明

危险分类

Flam. Gas 1 - Press. Gas Liquefied gas

储存分类代码

2A - Gases

WGK

nwg

闪点(°F)

-29.2 °F - closed cup

闪点(°C)

-34 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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分析证书(COA)

Lot/Batch Number

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Yonghui Zhang et al.
Journal of the American Chemical Society, 125(29), 8746-8747 (2003-07-17)
Hydrozirconation of cis-2-butene with Cp*ZrHCl[N(t-Bu)C(Me)N(Et)], generated in situ through hydrogenolysis of Cp*ZrCl(SiMe2Ph)[N(t-Bu)C(Me)N(Et)] (5), proceeds in high yield to produce a 1:2 mixture of the kinetically stable, diastereomeric sec-butyl complexes, 3a and 3b. Hydrozirconation of trans-2-butene under identical conditions provides a
Methylene, CH2. Stereospecific Reaction with cis-and trans-2-Butene.
Woodworth RC and Skell PS.
Journal of the American Chemical Society, 81(13), 3383-3386 (1959)
Duangkamol Gleeson
Journal of computer-aided molecular design, 22(8), 579-585 (2008-03-18)
In this study the results from a series of calculations are reported that probe the influence of the QM cluster size and the extended framework treatment in ONIOM calculations. This is done by comparing the differences in the structures and
Nadiya Bakhiya et al.
Archives of toxicology, 84(7), 563-578 (2010-03-20)
Furan is formed during commercial or domestic thermal treatment of food. The initial surveys of furan concentrations in heat-treated foods, published by European and US authorities, revealed the presence of relatively high furan levels in coffee, sauces, and soups. Importantly
Hao Ren et al.
The Journal of chemical physics, 133(6), 064702-064702 (2010-08-17)
Scanning tunneling microscopy (STM) topographical images and inelastic electron tunneling spectra (IETS) of a cis-2-butene molecule adsorbed on a Pd(110) surface have been simulated by first-principles calculations. Calculations have eliminated the ambiguity between the STM image and the adsorption orientation

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