240761
1-己烯
≥99%
别名:
1-n-Hexene
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关于此项目
线性分子式:
CH3(CH2)3CH=CH2
化学文摘社编号:
分子量:
84.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-753-1
Beilstein/REAXYS Number:
1209240
MDL number:
Assay:
≥99%
Form:
liquid
InChI key
LIKMAJRDDDTEIG-UHFFFAOYSA-N
InChI
1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
SMILES string
CCCCC=C
vapor density
3 (vs air)
vapor pressure
155 mmHg ( 21.1 °C)
assay
≥99%
form
liquid
autoignition temp.
487 °F
Quality Level
bp
60-66 °C (lit.)
density
0.678 g/mL at 25 °C (lit.)
functional group
allyl
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General description
1-己烯的聚合动力学已通过使用五锆胺双酚酸盐催化剂家族进行研究。由一系列铪配合物催化的1-己烯的聚合反应已有研究。
Application
- 1-己烯在高分子量聚合物中的合成：使用Lewis酸催化剂从1-己烯和丙烯酸甲酯合成高分子量共聚物，展示了材料科学领域的先进应用，特别是在开发耐用和多功能高分子材料方面（Wan et al., 2024）。
- 1-己烯在质子交换膜增强中的作用：利用1-己烯表征和增强功能多孔质子交换膜的物理化学性质，突出了它在提高燃料电池技术的能源效率和性能方面的关键作用（Ponomar et al., 2024）。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
Takahiro Yasumoto et al.
Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
Lingyan Gong et al.
Journal of colloid and interface science, 569, 219-228 (2020-03-01)
The current mechanism of surfactant enhanced oil recovery (EOR) mainly relies on forming middle-phase microemulsions to get ultra-low oil-water interfacial tension. However, residual oil can also be recovered using low concentration surfactant solutions without microemulsion formation, and the interaction between
Yuichi Ito et al.
Implant dentistry, 24(4), 477-479 (2015-06-04)
The evaluation of bone quality at the site of the alveolar bone for a dental implant is very important. This study presents an easy technique for direct evaluation of alveolar bone quality using nondecalcified cryofilm frozen sections on human alveolar
Chia-Hsiu Chen et al.
Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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