所有图片(1)
About This Item
线性分子式:
C2H5O2C(CH2)3P(C6H5)3Br
CAS号:
分子量:
457.34
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
质量水平
方案
97%
反应适用性
reaction type: C-C Bond Formation
mp
165-167 °C (lit.)
官能团
ester
phosphine
SMILES字符串
[Br-].CCOC(=O)CCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C24H26O2P.BrH/c1-2-26-24(25)19-12-20-27(21-13-6-3-7-14-21,22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h3-11,13-18H,2,12,19-20H2,1H3;1H/q+1;/p-1
InChI key
JPZMNVPVVYVXAD-UHFFFAOYSA-M
应用
Reactant for:
- Asymmetric synthesis of antihypercholesterolemic ezetimibe via Wittig reaction
- Wittig reactions
[3-(Ethoxycarbonyl)propyl]triphenylphosphonium bromide can be used:
- As a reactant in the synthesis of spirocyclic GPR119 agonists.
- In the synthesis of cyclic acetal intermediate of azadirachtin, a terpenoid found in the neem tree Azadirachta indica.
- To prepare a catechin metabolite named 5-(3,4,5-trihydroxyphenyl)valeric acid.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Synthetic studies of azadirachtin. Synthesis of the cyclic acetal intermediate in the naturally occurring form
Nishikimi Y, et al.
The Journal of Organic Chemistry, 54(14), 3354-3359 (1989)
Inhibitory activity of catechin metabolites produced by intestinal microbiota on proliferation of HeLa cells
Hara-Terawaki A, et al.
Biological & Pharmaceutical Bulletin, 40(8), 1331-1335 (2017)
Design and synthesis of novel and potent GPR119 agonists with a spirocyclic structure
Harada K, et al.
Bioorganic & medicinal chemistry letters, 28(7), 1228-1233 (2018)
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