130079
甲基三苯基溴化膦
98%
别名:
TPMP, Triphenylmethylphosphonium bromide, triphenylmethylphosphonium bromide
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关于此项目
线性分子式:
CH3P(C6H5)3Br
化学文摘社编号:
分子量:
357.22
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-218-9
Beilstein/REAXYS Number:
3599467
MDL number:
产品名称
甲基三苯基溴化膦, 98%
Quality Level
InChI key
LSEFCHWGJNHZNT-UHFFFAOYSA-M
InChI
1S/C19H18P.BrH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
SMILES string
[Br-].C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
assay
98%
form
powder
reaction suitability
reaction type: C-C Bond Formation
mp
230-234 °C (lit.)
functional group
phosphine
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Application
Wittig 烯化盐，最近用于合成烯炔，通过关环复分解反应生成苯并氮杂卓环系。
广泛应用于通过 Wittig 反应的亚甲基化作用
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 2
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
>464.0 °F
flash_point_c
> 240 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
监管及禁止进口产品
此项目有
E T Polymeropoulos et al.
Proceedings. Biological sciences, 279(1726), 185-193 (2011-06-03)
Metabolic rates of mammals presumably increased during the evolution of endothermy, but molecular and cellular mechanisms underlying basal metabolic rate (BMR) are still not understood. It has been established that mitochondrial basal proton leak contributes significantly to BMR. Comparative studies
Zhen Cheng et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 46(5), 878-886 (2005-05-06)
Numerous new molecular targets for diseases are rapidly being identified and validated in the postgenomic era, urging scientists to explore novel techniques for accelerating molecular probe development. In this study, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) was investigated as
M K Savage et al.
Archives of biochemistry and biophysics, 315(1), 142-152 (1994-11-15)
Treatment of isolated mitochondria with calcium and inorganic phosphate induces inner membrane permeability that is thought to be mediated through a non-selective, calcium-dependent pore. The inner membrane permeability results in the rapid efflux of small matrix solutes such as glutathione
Tammie Bishop et al.
American journal of physiology. Regulatory, integrative and comparative physiology, 282(2), R372-R382 (2002-01-17)
Cells isolated from the hepatopancreas of estivating snails (Helix aspersa) have strongly depressed mitochondrial respiration compared with controls. Mitochondrial respiration was divided into substrate oxidation (which produces the mitochondrial membrane potential) and ATP turnover and proton leak (which consume it).
Abhijit Mukhopadhyay et al.
Advanced drug delivery reviews, 59(8), 729-738 (2007-07-31)
Mitochondria is where the bulk of the cell's ATP is produced. Mutations occur to genes coding for members of the complexes involved in energy production. Some are a result of damages to nuclear coded genes and others to mitochondrial coded
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