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Merck
CN

130079

Sigma-Aldrich

甲基三苯基溴化膦

98%

别名:

TPMP, Triphenylmethylphosphonium bromide, triphenylmethylphosphonium bromide

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About This Item

线性分子式:
CH3P(C6H5)3Br
CAS号:
分子量:
357.22
Beilstein:
3599467
EC 号:
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

powder

反应适用性

reaction type: C-C Bond Formation

mp

230-234 °C (lit.)

SMILES字符串

[Br-].C[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H18P.BrH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1

InChI key

LSEFCHWGJNHZNT-UHFFFAOYSA-M

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应用

Wittig 烯化盐,最近用于合成烯炔,通过关环复分解反应生成苯并氮杂卓环系。
广泛应用于通过 Wittig 反应的亚甲基化作用

象形图

Skull and crossbonesEnvironment

警示用语:

Danger

危险声明

预防措施声明

危险分类

Acute Tox. 3 Oral - Aquatic Chronic 2

WGK

WGK 3

闪点(°F)

>464.0 °F

闪点(°C)

> 240 °C

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

监管及禁止进口产品

分析证书(COA)

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Synlett, 2771-2771 (2006)
Brian D Fink et al.
The Journal of pharmacology and experimental therapeutics, 342(3), 709-719 (2012-06-05)
Mitochondrial-targeted analogs of coenzyme Q (CoQ) are under development to reduce oxidative damage induced by a variety of disease states. However, there is a need to understand the bioenergetic effects of these agents and whether or not these effects are
Fengling Cui et al.
Journal of pharmaceutical and biomedical analysis, 43(3), 1033-1038 (2006-12-23)
A method for the determination of bismuth in pharmaceutical products using methyltriphenylphosphonium bromide as a molecular probe based on the resonance light scattering (RLS) technique was developed. In the presence of Tween-20, bismuth reacts with a large excess of I(-)
Abhijit Mukhopadhyay et al.
Advanced drug delivery reviews, 59(8), 729-738 (2007-07-31)
Mitochondria is where the bulk of the cell's ATP is produced. Mutations occur to genes coding for members of the complexes involved in energy production. Some are a result of damages to nuclear coded genes and others to mitochondrial coded
Duncan G G McMillan et al.
The Journal of biological chemistry, 282(24), 17395-17404 (2007-04-17)
Analysis of the atp operon from the thermoalkaliphilic Bacillus sp. TA2.A1 and comparison with other atp operons from alkaliphilic bacteria reveals the presence of a conserved lysine residue at position 180 (Bacillus sp. TA2.A1 numbering) within the a subunit of

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