281026
四丁基六氟磷酸铵
98%, powder
别名:
TBAPF6, Tetra-n-butylammonium hexafluorophosphate
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线性分子式:
(CH3CH2CH2CH2)4N(PF6)
化学文摘社编号:
分子量:
387.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
221-472-6
MDL number:
Beilstein/REAXYS Number:
4056584
产品名称
四丁基六氟磷酸铵, 98%
InChI key
BKBKEFQIOUYLBC-UHFFFAOYSA-N
InChI
1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC
assay
98%
form
powder
mp
244-246 °C (lit.)
Quality Level
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Application
六氟磷酸四丁基铵(TBAPF6)可用于：
- 用作通过Biginelli反应合成3,4-二氢嘧啶-2(1H)-酮和3,4-二氢嘧啶-2(1H)-硫酮衍生物的催化剂。
- 与六氟磷酸1-乙基-3-甲基咪唑鎓一起用作非水氧化还原液流电池中的载体电解质。
- 用作电聚合反应中的支持电解质。
六氟磷酸四丁基铵可用作载体电解质，通过二硫代苯胺的S-S偶联，形成3,5-二亚氨基-1,2-二硫代戊环衍生物的环状二硫键部分。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Alkylammonium and alkylimidazolium perhaloborates, phosphates, and aluminates as catalysts in the Biginelli reaction
Putilova ES et al.
Russ. J. Org. Chem., 41(4), 512-516 (2005)
The application of a non-aqueous bis (acetylacetone) ethylenediamine cobalt electrolyte in redox flow battery
Zhang D, et al.
Journal of Power Sources, 217, 199-203 (2012)
Holger Hartleb et al.
ACS nano, 9(10), 10461-10470 (2015-09-19)
We have investigated the photophysical properties of electrochemically gate-doped semiconducting single-wall carbon nanotubes (s-SWNTs). A comparison of photoluminescence (PL) and simultaneously recorded absorption spectra reveals that free-carrier densities correlate well with the first sub-band exciton or trion oscillator strengths but
Tetrabutylammonium hexafluorophosphate and 1-ethyl-3-methyl imidazolium hexafluorophosphate ionic liquids as supporting electrolytes for non-aqueous vanadium redox flow batteries
Zhang D, et al.
Journal of Power Sources, 203, 201-205 (2012)
Electrochemical synthesis and properties of copolymers based on N-alkylpyrroles and thiophene
Vautrin M, et al.
Electrochemical Communications, 1(6), 233-237 (1999)
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