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质量水平
检测方案
95%
形式
liquid
折射率
n20/D 1.414 (lit.)
bp
52-53 °C/175 mmHg (lit.)
密度
0.868 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C[Si](C)(C)N=[N+]=[N-]
InChI
1S/C3H9N3Si/c1-7(2,3)6-5-4/h1-3H3
InChI key
SEDZOYHHAIAQIW-UHFFFAOYSA-N
一般描述
叠氮基三甲基硅烷（TMSN3）是一种无色稳定的有机硅烷试剂。其在高温下分解非常缓慢。 它是一种非常常用的叠氮化物来源，已用于合成氨基三唑配体。通过将氯三甲基硅烷滴加到搅拌的NaN3 二甘醇二甲醚溶液中，可以非常容易地合成叠氮基三甲基硅烷。
应用
叠氮三甲基硅烷可用作：
- 通过金属有机化学气相沉积方法制备 GaN 纳米线的氮前驱体。
- Li-O2 电池中的电解质添加剂。TMSN3 的加入可形成坚固的固体电解质界面。
- 这是合成四唑、富勒烯叠氮和 α-叠氮肟的有效试剂。
- 是醇和酚的 O-三甲基甲硅烷基化中的甲硅烷基化度试剂。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Covalent functionalization of epitaxial graphene by azidotrimethylsilane
Choi, Junghun, et al.
The Journal of Physical Chemistry C, 113(22), 9433-9435 (2009)
Synthesis, 106-106 (1988)
Azidotrimethylsilane
Li, B. L.
Synlett, 23(10), 1554-1555 (2012)
Journal of the American Chemical Society, 116, 4501-4501 (1994)
James T Goettel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(5), 1136-1143 (2019-11-30)
A cyclic (alkyl)(amino)carbene (CAAC) has been shown to react with a covalent azide similar to the Staudinger reaction. The reaction of Me CAAC with trimethylsilyl azide afforded the N-silylated 2-iminopyrrolidine (Me CAAC=NSiMe3 ), which was fully characterized. This compound undergoes
商品
Click chemistry, and the copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) in particular, is a powerful new synthetic tool in polymer chemistry and material science.
Since the preparation of the first organic azide, phenyl azide, by Peter Griess in 1864 this energy-rich and versatile class of compounds has enjoyed considerable interest.
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