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Merck
CN
  • Addition reaction of dialkyl disulfides to terminal alkynes catalyzed by a rhodium complex and trifluoromethanesulfonic acid.

Addition reaction of dialkyl disulfides to terminal alkynes catalyzed by a rhodium complex and trifluoromethanesulfonic acid.

Organic letters (2001-03-22)
M Arisawa, M Yamaguchi
摘要

[reaction: see text]. Addition of dialkyl disulfides to terminal alkynes is catalyzed by a rhodium-phosphine complex and trifluoromethanesulfonic acid giving (Z)-bis(alkylthio)olefins stereoselectively.

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Sigma-Aldrich
三氟甲磺酸, ReagentPlus®, ≥99%
Sigma-Aldrich
三氟甲磺酸, reagent grade, 98%