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Merck
CN

77025AST

Supelco

Astec ® CHIRALDEX B-DM 毛细管 GC 色谱柱

L × I.D. 50 m × 0.25 mm, df 0.12 μm

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别名:
GC column, chiral, beta-dextran
UNSPSC代码:
41115710
NACRES:
SB.54

物料

fused silica

质量水平

描述

GC capillary column

包装

pkg of 1 ea

参数

-10-200 °C temperature (isothermal)
-10-220 °C temperature (programmed)

β值

500

df

0.12 μm

技术

gas chromatography (GC): suitable

长度 × 内径

50 m × 0.25 mm

基质活性基团

non-bonded; 2,3-di-O-methyl-6-t-butyl silyl derivative of β-cyclodextrin phase

应用

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

色谱柱类型

capillary chiral

分离技术

chiral

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一般描述

通过特殊的衍生方法,CHIRALDEX B-DM 中环糊精的浓度在聚硅氧烷载体中显著增加。该固定相对许多游离酸和碱非常有用。B-DM 能够分离可在全甲基化 β 环糊精固定相所分离的大部分物质,但分离度更高。B-DM 的选择性包括了 B-PM 和 B-PH 相的应用,但性能更加出众。

化学/物理抗性

温度限制:
  • -10°C 至 200°C 等温,220°C 程序性的

其他说明

We offer a variety of chromatography accessories including analytical syringes

法律信息

Astec is a registered trademark of Merck KGaA, Darmstadt, Germany
CHIRALDEX is a trademark of Sigma-Aldrich Co. LLC

法规信息

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Rh-catalyzed asymmetric hydrogenation using a furanoside monophosphite second-generation ligand library: scope and limitations
Alegre, Sabina, et al.
Tetrahedron, 25 (3), 258-262 (2014)
Synthesis of a chiral asymmetrical NCN ligand and its metallation
Sylla Dieng, Pape,et al.
Comptes Rendus Chimie, 12 (5), 560-564 (2009)
J Mydlová et al.
Journal of chromatography. A, 1150(1-2), 124-130 (2007-03-24)
The enantiomers of dialkyl 2,3-pentadienedioate undergo interconversion during gas chromatographic separation on chiral stationary phases. In this paper the on-column apparent interconversion kinetic and thermodynamic activation data were determined for dimethyl, diethyl, propylbutyl and dibutyl 2,3-pentadienedioate enantiomers by gas chromatographic
Evaluating dynamic kinetic resolution strategies in the asymmetric hydrosilylation of cyclic ketimines
Jones, Simon; Zhao, Peichao
Tetrahedron, 25 (3), 238-244 (2014)
Ionic cyclodextrins in ionic liquid matrices as chiral stationary phases for gas chromatography
Huang, Ke, et al.
Tetrahedron Asymmetry, 1217 (32), 5261-5273 (2010)

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

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