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Merck
CN

502219

Supelco

4-二甲胺基苯基偶氮苯磺酰氯

for HPLC derivatization

别名:

4-(二甲氨基)偶氮苯-4′-磺酰氯, 4-(N,N-二甲基氨基)偶氮苯-4'-磺酸氯, 4-二甲胺基苯基偶氮苯磺酰氯, DABS-Cl

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About This Item

线性分子式:
(CH3)2NC6H4N=NC6H4SO2Cl
CAS号:
分子量:
323.80
Beilstein:
3064095
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:

等级

for HPLC derivatization

表单

solid

包装

pkg of 500 mg

mp

185 °C (dec.) (lit.)

储存温度

room temp

SMILES字符串

CN(C)c1ccc(cc1)\N=N\c2ccc(cc2)S(Cl)(=O)=O

InChI

1S/C14H14ClN3O2S/c1-18(2)13-7-3-11(4-8-13)16-17-12-5-9-14(10-6-12)21(15,19)20/h3-10H,1-2H3/b17-16+

InChI key

VTVWTPGLLAELLI-WUKNDPDISA-N

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一般描述

丹磺酰氯(4-二甲基氨基偶氮苯-4′-磺酰氯)是用于HPLC的衍生化氨基酸的发色标记试剂。它可与所有氨基酸自由地发生反应,形成丹磺酰氨基酸,这些氨基酸具有光稳定性,可以在薄层色谱板上观察到。

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象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chromophoric labeling of amino acids with 4-dimethylaminoazobenzene-4'-sulfonyl chloride.
J K Lin and J Y Chang.
Analytical Chemistry, 47 (9), 1634-1638 (1975)
Jansen, E.H.J., et al.
Journal of Chromatography A, 553 (1991)
K Sormiachi et al.
Journal of chromatography. B, Biomedical applications, 664(2), 435-439 (1995-02-17)
A high-performance liquid chromatographic method was modified for the determination of hydroxyproline in cultured cells derived from rat liver. First, the primary amino group in the cell hydrolysate was blocked with o-phthalaldehyde, then the secondary amino group was derivatized with
M Takahashi et al.
Journal of chromatography. B, Biomedical sciences and applications, 688(2), 197-203 (1997-01-24)
To elucidate the factors involved in dry skin and the skin damage caused by UV light, it is necessary to analyze small amounts of stratum corneum to determine amino acid contents. A new assay method for this purpose is described.
Kai-Yang Syu et al.
Journal of agricultural and food chemistry, 56(17), 7637-7643 (2008-07-26)
Dabsyl chloride (dimethylaminoazobenzene sulfonyl chloride), a useful chromophoric labeling reagent for amino acids and amines, was developed in this laboratory in 1975. Although several methods have been developed to determine various types of amino acids, a quick and easy method

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