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Merck
CN

G3267

Sigma-Aldrich

甘氨酸苄酯 盐酸盐

≥98% (TLC)

别名:

甘氨酸苄酯

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About This Item

经验公式(希尔记法):
C9H11NO2 · HCl
CAS号:
分子量:
201.65
MDL编号:
UNSPSC代码:
12352209
eCl@ss:
32160406
PubChem化学物质编号:
NACRES:
NA.26

product name

甘氨酸苄酯 盐酸盐,

检测方案

≥98% (TLC)

质量水平

形式

powder

颜色

white

储存温度

−20°C

SMILES字符串

Cl.NCC(=O)OCc1ccccc1

InChI

1S/C9H11NO2.ClH/c10-6-9(11)12-7-8-4-2-1-3-5-8;/h1-5H,6-7,10H2;1H

InChI key

VLQHNAMRWPQWNK-UHFFFAOYSA-N

应用

甘氨酸苄基酯可在缩合反应中用作有机试剂。

生化/生理作用

氨基酸单体的苯甲酯基团提高酶的底物亲和力和专一性,从而促进多肽的动力学控制合成(KCS)。它可用于甘氨酸单体的酶促化学聚合反应。

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

新产品

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J Martinez et al.
Carbohydrate research, 50(1), 15-22 (1976-08-01)
An O-glycodipeptide was synthesized by lengthening the peptide chain on the C-terminal side of a glycosylamino acid unit. N-(Benzyloxycarbonyl)-3-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-L-threonine o-nitrophenyl ester and pentachlorophenyl ester were condensed with glycine benzyl ester to give both the same glycodipeptide, [N-(benzyloxycarbonyl)-3-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-L-threonyl]glycine benzyl ester (9).
V Maurich et al.
Farmaco (Societa chimica italiana : 1989), 49(12), 805-808 (1994-12-01)
The synthesis of 2-(4-amino-5-chloro-2-methoxybenzamido)acetic acid 2, a metabolite of metoclopramide 1, has been accomplished through the coupling of 4-amino-5-chloro-2-methoxybenzoic acid 4 with glycine benzyl ester followed by a catalytic hydrogenation. Such a metabolite could not be detected directly in the
Jose Manuel Ageitos et al.
Biomacromolecules, 17(1), 314-323 (2015-12-02)
The chemoenzymatic polymerization of amino acid monomers by proteases involves a two-step reaction: the formation of a covalent acyl-intermediate complex between the protease and the carboxyl ester group of the monomer and the subsequent deacylation of the complex by aminolysis

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