等级
ACS reagent
NMR grade
质量水平
蒸汽压
11.66 psi ( 20 °C)
检测方案
≥99.9%
形式
liquid
自燃温度
842 °F
expl. lim.
0.34-6.3 %
技术
NMR: suitable
蒸发残留物
≤0.05%
折射率
n20/D 1.358 (lit.)
bp
26-28 °C (lit.)
mp
−99 °C (lit.)
密度
0.648 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C[Si](C)(C)C
InChI
1S/C4H12Si/c1-5(2,3)4/h1-4H3
InChI key
CZDYPVPMEAXLPK-UHFFFAOYSA-N
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应用
四甲基硅烷可用作：
- 前体，通过化学气相沉积法合成α-SiC。
- 反应物，在氯化铝和二氯甲烷环境下由金刚烷合成1,3,5,7-四甲基金刚烷。
- 溶剂，用于1-辛烯与吗啉的氢胺甲基化。
- 甲基化试剂，将四氯化锗转化为四甲基锗、三甲基氯化锗、二甲基氯化锗或三氯化甲基锗。
警示用语：
Danger
危险声明
预防措施声明
危险分类
Flam. Liq. 1
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
危险化学品
Tetramethylsilane in synthesis: selective mono-and polymethylations of germanium tetrachloride
Bordeau M, et al.
Organometallics, 1087-1089, 4-4 (1985)
Synthesis of alpha-SiC from tetramethylsilane by chemical vapor deposition at high temperature
Jeong S, et al.
Applied Physics Express, 7, 025501-025501 (2014)
A novel approach to selecting thermomorphic multicomponent solvent systems (TMS) for hydroaminomethylation reactions
Behr A, et al.
Chemical Engineering and Processing, 69, 15-23 (2013)
James C Salamanca et al.
Scientific reports, 8(1), 7559-7559 (2018-05-17)
E-cigarette aerosol emission studies typically focus on benchmarking toxicant levels versus those of cigarettes. However, such studies do not fully account for the distinct chemical makeup of e-liquids and their unique properties. These approaches often conclude that there are fewer
Exhaustive One-Step Bridgehead Methylation of Adamantane Derivatives with Tetramethylsilane
Bonsir M, et al.
European Journal of Organic Chemistry, 2021, 5227-5237 (2021)
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