等级
ACS reagent
质量水平
蒸汽密度
3 (vs air)
蒸汽压
27 mmHg ( 20 °C)
40 mmHg ( 25 °C)
检测方案
≥99.0%
形式
liquid
自燃温度
356 °F
expl. lim.
22 %
技术
thin layer chromatography (TLC): suitable
杂质
≤0.0016 meq/g Titr. acid
≤0.005% Peroxide as (H2O2)
≤0.01% Carbonyl (as HCHO)
≤0.05% water
蒸发残留物
≤0.005%
颜色
APHA: ≤20
折射率
n20/D 1.422 (lit.)
pH值(酸碱度)
6.0-8 (20 °C, 500 g/L)
bp
100-102 °C (lit.)
mp
10-12 °C (lit.)
转变温度
freezing point ≥11.0
密度
1.034 g/mL at 25 °C (lit.)
SMILES字符串
C1COCCO1
InChI
1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2
InChI key
RYHBNJHYFVUHQT-UHFFFAOYSA-N
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一般描述
1,4-二恶烷被广泛用作工业中各种有机化合物的溶剂。它是在工业废水中发现的一种不可生物降解的污染物。它通过使用氧气和臭氧而进行的氧化降解,有助于将其转化为可生物降解的产物,并可通过常规方法轻松去除。
应用
1,4-二恶烷可用作N-(4-(丙-2-炔基氧基)苯基)乙酰胺和3-(4-(丙-2-炔氧基)苯基)-3,4-二氢-2H-苯并[e][1,3]恶嗪合成中的溶剂。
警示用语:
Danger
危险分类
Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
危险化学品
Oxidation and biodegradability enhancement of 1,4-dioxane using hydrogen peroxide and ozone.
Environmental science & technology, 28(11), 1812-1818 (1994-10-01)
Self-curable benzoxazine functional polybutadienes synthesized by click chemistry.
Designed Monomers and Polymers, 12(2), 167-176 (2009)
Alkene trifluoromethylation coupled with C-C bond formation: construction of trifluoromethylated carbocycles and heterocycles.
Angewandte Chemie (International ed. in English), 52(14), 4000-4003 (2013-02-27)
ChemSusChem, 5(9), 1737-1742 (2012-07-05)
The dehydration of D-fructose to 5-hydroxymethylfurfural was studied under single-phase conditions in the low boiling solvent 1,4-dioxane at moderate temperatures in the presence of the solid acid-catalyst Amberlyst-15. The reaction was first examined and optimized under batch conditions, where it
Water research, 47(5), 1919-1927 (2013-02-09)
This paper reports on the reusability and the optimal reuse of iron-rich sludge for an electrochemical Fenton-type process using sequencing batch mode and separation batch mode reuse models. In the sequencing batch mode, processes of electrochemical treatment, neutralization, sedimentation, and
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