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Merck
CN

S8032

Sigma-Aldrich

叠氮化钠

BioXtra

别名:

NSC 3072, 叠氮酸 钠盐

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About This Item

线性分子式:
NaN3
CAS号:
分子量:
65.01
EC 号:
MDL编号:
UNSPSC代码:
12352201
PubChem化学物质编号:
NACRES:
NA.21

生物来源

synthetic

质量水平

产品线

BioXtra

检测方案

99.8%

形式

powder or crystals

杂质

≤0.1% Insoluble matter

mp

370-425 °C

溶解性

H2O: 1 M at 20 °C, clear, colorless

痕量阴离子

chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.005%

痕量阳离子

Al: ≤0.0005%
Ca: ≤0.005%
Cu: ≤0.0005%
Fe: ≤0.0005%
K: ≤100 mg/kg
Mg: ≤0.001%
Pb: ≤0.001%
Zn: ≤0.0005%

吸光度

<1.0 at 276

SMILES字符串

[Na]N=[N+]=[N-]

InChI

1S/N3.Na/c1-3-2;/q-1;+1

InChI key

PXIPVTKHYLBLMZ-UHFFFAOYSA-N

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应用

有机叠氮化合物

的加氢叠氮化催化剂:
  • 氧化脱羧
  • Michael加成反应


  • 蓝色荧光共聚物的合成试剂
  • 金属膦酸盐
  • 氨基化芳烃

参与哌唑嗪B的合成

警示用语:

Danger

危险分类

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral

靶器官

Brain

补充剂危害

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

监管及禁止进口产品

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分析证书(COA)

Lot/Batch Number

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访问文档库

Y. Wada, et al.,
Tetrahedron, 65, 1059-1062 (2009)
H. Chen, et al.,
Macromolecules, 43, 3613-3623 (2010)
Xiaohua Sun et al.
Organic letters, 9(22), 4495-4498 (2007-10-04)
A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of beta-alkyl nitroalkenes and alpha,beta-unsaturated ketone/esters, producing an allylic nitro compound in good to
V. N. Telvekar and K. A. Sasane,
Synlett, 18, 2778-2780 (2010)
Deng-Ke Cao et al.
Inorganic chemistry, 44(10), 3599-3604 (2005-05-10)
Based on the [hydroxy(4-pyridyl)methyl]phosphonate ligand, three compounds with formula Ni{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (1), Cd{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (2), and Gd{(4-C(5)H(4)N)CH(OH)P(OH)O(2)}(3).6H(2)O (3) have been synthesized under hydrothermal conditions. The crystal data for 1 are as follows: orthorhombic, space group Pbca, a = 8.7980(13) A, b =

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