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Merck
CN

87208

Supelco

溴化十四烷基三甲基铵

suitable for ion pair chromatography, LiChropur, ≥99.0% (AT)

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别名:
三甲基(十四烷基)溴化铵, 十四烷基三甲基溴化铵
线性分子式:
CH3(CH2)13N(Br)(CH3)3
CAS号:
分子量:
336.39
Beilstein:
3633227
EC 号:
MDL编号:
UNSPSC代码:
12000000
PubChem化学物质编号:
NACRES:
NB.21

描述

cationic

质量水平

检测方案

≥99.0% (AT)

形式

crystals

质量

LiChropur

分子量

micellar avg mol wt 27,000

聚集数

80

技术

ion pair chromatography: suitable

CMC

4-5 mM (20-25°C)

mp

245-250 °C (lit.)

λ

10 % in H2O

紫外吸收

λ: 240 nm Amax: ≤0.08
λ: 250 nm Amax: ≤0.05
λ: 260 nm Amax: ≤0.04
λ: 500 nm Amax: ≤0.02

适用性

corresponds to standard for filter test

SMILES字符串

[Br-].CCCCCCCCCCCCCC[N+](C)(C)C

InChI

1S/C17H38N.BrH/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18(2,3)4;/h5-17H2,1-4H3;1H/q+1;/p-1

InChI key

CXRFDZFCGOPDTD-UHFFFAOYSA-M

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一般描述

Ion-pairing reagents as mobile phase additives facilitate the separation of ionic and highly polar substances on reversed phase HPLC columns. Their purity is an important parameter for their successful application. Sigma-Aldrich offers an wide range of tailor-made reagents for anionic (quaternary ammonium and phosphonium salts) and cationic (alkanesulfonates) analyzes. All mobile phase additives are subject to rigorous testing with special emphasis on the requirements of modern reversed phase HPLC:

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法律信息

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT RE 2 Oral - STOT SE 3

靶器官

Gastrointestinal tract, Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Dulan B Gunasekara et al.
Electrophoresis, 32(8), 832-837 (2011-03-26)
The combination of microchip electrophoresis with amperometric detection leads to a number of analytical challenges that are associated with isolating the detector from the high voltages used for the separation. While methods such as end-channel alignment and the use of
Hayat M Marafie et al.
Talanta, 91, 26-32 (2012-03-01)
Two conventional plastic membrane electrodes that are selective for the tetradecyltrimethylammonium cation (TTA) have been prepared. The ion exchangers of these sensors were the ion associate, TTA-PT, and the ion aggregate, TTA-PSS, where PT and PSS are phosphotungstate and polystyrene
Yan Jiang et al.
The journal of physical chemistry. B, 113(24), 8357-8361 (2009-05-26)
Three kinds of conventional surfactants, namely, two nonionic surfactants [polyethylene glycol (23) lauryl ether (Brij-35) and Triton X-100 (TX-100)], one cationic surfactant [n-tetradecyltrimethyl ammonium bromide (TTAB)], and an anionic surfactant [sodium n-dodecyl sulfate (SDS)}, were mixed into the quaternary ammonium
Yuri Borodko et al.
Langmuir : the ACS journal of surfaces and colloids, 25(12), 6665-6671 (2009-04-29)
The vibrational spectra of platinum nanoparticles (12 nm) capped with tetradecyltrimethylammonium bromide, C(14)TAB, were investigated by Fourier transform infrared (FTIR) spectroscopy. We have shown that the thermal decay of Pt-C(14)TAB nanoparticles in N(2), H(2), and O(2) atmospheres leads to the
Aline Delbos et al.
Physical review. E, Statistical, nonlinear, and soft matter physics, 84(1 Pt 1), 011404-011404 (2011-08-27)
We investigate experimentally the behavior of liquid foams pumped at a given flow rate through a single pore, in the situation where the pore diameter is smaller than the bubble diameter. Results reveal that foam invasion can be observed only

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