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安全信息

62118

Supelco

(R)-(+)-柠檬烯

analytical standard

别名:

(+)-对薄荷-1,8-二烯, (+)-香芹烯, (R)-4-异丙烯基-1-甲基-1-环己烯

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About This Item

经验公式（希尔记法）:
C10H16
CAS号:
5989-27-5
分子量:
136.23
Beilstein:
2204754
EC 号:
227-813-5
MDL编号:
MFCD00062991
UNSPSC代码:
85151701
PubChem化学物质编号:
329759707
NACRES:
NA.24
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等级

analytical standard

质量水平

100

蒸汽密度

4.7 (vs air)

蒸汽压

<3 mmHg ( 14.4 °C)

方案

≥99.0% (sum of enantiomers, GC)

旋光性

[α]20/D +115.5±1°, c = 10% in ethanol

保质期

limited shelf life, expiry date on the label

expl. lim.

6.1 %

技术

HPLC: suitable
gas chromatography (GC): suitable

折射率

n20/D 1.473 (lit.)
n20/D 1.473

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此商品
CRM4042262122818407
(R)-(+)-Limonene analytical standard

62118

(R)-(+)-Limonene

(R)-(+)-Limonene solution certified reference material, 2000&#160;&#956;g/mL in methanol, ampule of 1&#160;mL

CRM40422

(R)-(+)-Limonene solution

(R)-(+)-Limonene technical, ~90% (sum of enantiomers, GC)

62122

(R)-(+)-Limonene

(R)-(+)-Limonene for synthesis

818407

(R)-(+)-Limonene

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

gas chromatography (GC): suitable

technique(s)

-

technique(s)

-

format

neat

format

single component solution

format

-

format

-

Quality Level

100

Quality Level

300

Quality Level

100

Quality Level

200

grade

analytical standard

grade

certified reference material, TraceCERT®

grade

-

grade

-

assay

≥99.0% (sum of enantiomers, GC)

assay

-

assay

~90% (sum of enantiomers, GC)

assay

≥94.0% (GC)

一般描述

(R)-(+)-柠檬烯是环状单萜柠檬烯的 R-和主要对映体。它是从橙子、葡萄柚和柠檬中提取的精油的主要成分。此外，它还作为调味剂添加到不同的个人和家庭清洁产品、饮料和糖果产品中。众所周知，它具有抗氧化、抗菌、抗真菌、抗炎和抗癌特性。[1][1]

应用

该分析标准也可按如下方式使用：
  • 采用两种新型电化学传感器的差分脉冲伏安法测定酒精饮料中的 (R)-(+)-柠檬烯
  • 采用二维高效液相色谱-电喷雾串联质谱法（ESI-MS/MS）同时测定 10 种香水产品样品中的柠檬烯和芳樟醇
  • 采用多维气相色谱-质谱联用技术测定柑橘属 3 种植物中挥发性手性化合物的对映体组成
  • 采用气相色谱-火焰离子化检测器（GC-FID）对野生和栽培茴香中挥发物和脂肪酸的多残留分析

其他说明

This compound is commonly found in plants of the genus: carum mentha salvia
环外双键的区域选择性加氢反应[2][3]；桥环双键的区域选择性环氧化反应[4]

警示用语：

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

123.8 °F - closed cup

闪点(°C)

51 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

    • 历史批次信息供参考:

    分析证书(COA)

    Lot/Batch Number
    BCCL3945
    BCCG5088
    BCCD9739
    BCBX5942
    BCBR6161V

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    Whitefly attraction to rosemary (Rosmarinus officinialis L.) is associated with volatile composition and quantity
    Sadeh D, et al.
    PLoS ONE, 12(5) (2017)
    Giuseppe Ferrandino et al.
    Clinical and translational gastroenterology, 11(9), e00239-e00239 (2020-10-24)
    Liver cirrhosis and its complication - hepatocellular carcinoma (HCC) - have been associated with increased exhaled limonene. It is currently unclear whether this increase is more strongly associated with the presence of HCC or with the severity of liver dysfunction.
    R. Baker et al.
    Journal of the Chemical Society. Chemical Communications, 414-414 (1987)
    Rebecca Jordan et al.
    Neuron, 98(6), 1214-1228 (2018-06-05)
    The olfactory bulb (OB) is the first site of synaptic odor information processing, yet a wealth of contextual and learned information has been described in its activity. To investigate the mechanistic basis of contextual modulation, we use whole-cell recordings to
    T. Kitahara et al.
    Tetrahedron, 43, 2689-2689 (1987)
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    气相色谱分析(GC)是分离和分析混合物中挥发性和半挥发性化合物的常用分析技术。这一技术凭借出色的分辨能力及速率和灵敏度，成为常用的分析技术。GC在环境、石油、化工、食品和饮料以及制药等众多行业中广泛使用。

    Chromatograms

    suitable for GC

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