46264
二茂铁甲酸
≥96%, purum
别名:
二茂铁羧酸
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关于此项目
经验公式（希尔记法）:
C11H10FeO2
化学文摘社编号:
分子量:
230.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-040-6
MDL number:
产品名称
二茂铁甲酸, purum, ≥96%
InChI
1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;
InChI key
VUJLGCHOGQEAED-UHFFFAOYSA-N
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.OC(=O)[C]2[CH][CH][CH][CH]2
grade
purum
assay
≥96%
reaction suitability
core: iron, reagent type: catalyst
mp
210 °C (dec.) (lit.)
Quality Level
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General description
Ferrocene carboxylic acid (FCCa) is an organometallic compound comprised of a ferrocene core with a carboxylic acid functional group. It is used as a mediator in electrocatalytic oxidation. Due to its excellent redox properties, it is widely used in electrochemistry, redox probes, and peptide chain modifications. In addition, a direct cross-coupling reaction was explored using ferrocenecarboxylic acid and alkenes.
Application
Ferrocene carboxylic acid can be used as a:
- Starting material in the synthesize of ferrocene-guanine conjugates.
- Redox mediator in electrochemical-chemical-chemical (ECC) redox cycling.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
涉药品监管产品
此项目有
Palladium (II)-Catalyzed Enantioselective C- H Alkenylation of Ferrocenecarboxylic Acid
Huang Y, et al.
Advanced Synthesis & Catalysis, 362(6), 1385-1390 (2020)
New chiral ferrocenyl amidophosphine ligand for remarkable improvement of enantioselectivities in copper-catalyzed addition of diethylzinc to N-sulfonylimines
Wang MC, et al.
Tetrahedron Letters, 46(32), 5413-5416 (2005)
New approaches toward ferrocene--guanine conjugates: synthesis and electrochemical behavior
Iurlo M, et al.
Organometallics, 33(18), 4986-4993 (2014)
Simultaneous electrochemical determination of glutathione and tryptophan on a nano-TiO2/ferrocene carboxylic acid modified carbon paste electrode
Raoof JB, et al.
Sensors and Actuators B, Chemical, 143(1), 261-269 (2009)
Huilan Su et al.
Biosensors & bioelectronics, 26(11), 4601-4604 (2011-05-31)
A multiple amplification immunoassay was proposed to detect alpha-fetoprotein (AFP), which was based on ferrocenemonocarboxylic-HRP conjugated on Pt nanoparticles as labels for rolling circle amplification (RCA). Firstly, the capture antibody (anti-AFP) was immobilized on glass carbon electrode (GCE) deposited nano-sized
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