所有图片(1)
别名:
2,4-戊二酮 铁(III) 衍生物, 2，4-戊二酮铁（III）, Fe(acac)3, 乙酰丙酮铁
线性分子式:
Fe(C5H7O2)3
CAS号:
分子量:
353.17
Beilstein:
4157960
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.23
推荐产品
等级
purum
质量水平
检测方案
≥97.0% (RT)
形式
powder
反应适用性
core: iron
reagent type: catalyst
mp
180-182 °C (dec.) (lit.)
180-190 °C (dec.)
密度
5.24 g/mL at 25 °C (lit.)
SMILES字符串
CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
InChI
1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
InChI key
AQBLLJNPHDIAPN-LNTINUHCSA-K
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一般描述
Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.
应用
Iron(III) acetylacetonate can be used as:
- A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.
- A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
- A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.
- A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.
- A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.
用于高结晶（Zn，Fe）Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
其他说明
用于格氏反应的催化剂，添加酸性氯化物可生成酮。
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
C. Cardellicchio et al.
Tetrahedron Letters, 28, 2053-2053 (1987)
V. Fiandanese et al.
Tetrahedron Letters, 25, 4805-4805 (1984)
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Michael Challenor et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16780-16787 (2014-10-07)
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles and upconverting NaYF4:Yb,Er nanoparticles co-encapsulated within a poly(glycidyl methacrylate) sphere.
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