44920
乙酰丙酮铁 III
purum, ≥97.0% (RT)
别名:
2,4-戊二酮 铁(III) 衍生物, 2，4-戊二酮铁（III）, Fe(acac)3, 乙酰丙酮铁
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线性分子式:
Fe(C5H7O2)3
化学文摘社编号:
分子量:
353.17
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
237-853-5
Beilstein/REAXYS Number:
4157960
MDL number:
产品名称
乙酰丙酮铁 III, purum, ≥97.0% (RT)
InChI key
AQBLLJNPHDIAPN-LNTINUHCSA-K
InChI
1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
SMILES string
CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
grade
purum
assay
≥97.0% (RT)
form
powder
reaction suitability
core: iron
reagent type: catalyst
Quality Level
greener alternative product characteristics
Catalysis
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mp
180-182 °C (dec.) (lit.)
180-190 °C (dec.)
density
5.24 g/mL at 25 °C (lit.)
greener alternative category
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Application
用于高结晶（Zn，Fe）Fe2O4 薄膜的 MOCVD 前体和这些薄膜的磁性测量。
Iron(III) acetylacetonate can be used as:
- A precursor in the synthesis of Fe3O4/carbon composite fibers via forcespinning. This fiber material is suitable for use as anode materials in lithium-ion batteries.
- A precursor in the synthesis of iron-based metal-organic frameworks (MOFs) for the applications in rechargeable alkali-ion batteries.
- A catalyst in the controlled living radical polymerization of vinyl acetate to synthesis of polymers with controlled molecular weights.
- A precursor to synthesize iron-doped titania (Fe-TiO2) photocatalysts for the potential applications in photocatalytic reactions.
- A MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.
- A precursor in the synthesis of Iron-oxide nanoparticles in the development of carbon nanofiber (CNF) based anodes for lithium-ion batteries.
- A precursor in the synthesis of ferrimagnetic iron oxide nanoparticles (magnetite or maghemite) with various morphologies, which are employed in biomedical applications such as hyperthermia, magnetic resonance imaging (MRI), and drug delivery.
- A precursor in the synthesis of magnetite nanoparticles via solvothermal synthesis. The resulting nanoparticles are smaller than 20 nm, exhibit uniform size, high crystallinity, and good dispersibility in organic solvents. These properties make them suitable for applications in, nanocomposite preparation, and film deposition. (3)
- A precursor in the synthesis of superparamagnetic iron oxide nanoparticles by various methods such as gas-phase deposition, pulsed laser ablation, power ball milling, chemical co-precipitation, micro-emulsions, hydrothermal synthesis. These nanoparticles find applications in tissue engineering biosensors, magnetic resonance imaging.
Other Notes
用于格氏反应的催化剂，添加酸性氯化物可生成酮。
Features and Benefits
Iron(III) acetylacetonate exhibits
- Ethanol, Acetone, Benzene, dichloromethane, Toluene, Chloroform
- Suitable for Iron catalysed cross-coupling reaction
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General description
Iron(III) acetylacetonate, also known as tris(acetylacetonato)iron(III) or Fe(acac)3, is a coordination compound that is highly soluble in organic solvents. It is used as a precursor in the preparation of iron-containing materials and thin films, which are important in electronics and coatings. Additionally, it is also as a catalyst in organic reactions, particularly in the synthesis of organic compounds and polymerization processes.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
V. Fiandanese et al.
Tetrahedron Letters, 25, 4805-4805 (1984)
C. Cardellicchio et al.
Tetrahedron Letters, 28, 2053-2053 (1987)
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure
Michael Challenor et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16780-16787 (2014-10-07)
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles and upconverting NaYF4:Yb,Er nanoparticles co-encapsulated within a poly(glycidyl methacrylate) sphere.
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