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Merck
CN

00942

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide

for GC derivatization, LiChropur, ≥95.0% (GC), with 1% tert-Butyldimethylchlorosilane

别名:

N-甲基-N-叔丁基二甲基甲硅烷基三氟乙酰胺, MTBSTFA + 1% TBDMSCl, 甲硅烷基化混合物VI

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关于此项目

经验公式(希尔记法):
C9H18F3NOSi
化学文摘社编号:
分子量:
241.33
UNSPSC Code:
41116105
PubChem Substance ID:
NACRES:
NA.22
Beilstein/REAXYS Number:
3606546
MDL number:
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产品名称

N-叔丁基二甲基甲硅烷基-N-甲基三氟乙酰胺,含 1% 叔丁基二甲基氯硅烷, LiChropur, ≥95.0% (GC)

SMILES string

CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C

InChI key

QRKUHYFDBWGLHJ-UHFFFAOYSA-N

InChI

1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3

grade

derivatization grade ((GC derivatization))

assay

≥95.0% (GC)

form

liquid

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Silylations

technique(s)

gas chromatography (GC): suitable

impurities

0.5-1.5% tert-butyldimethylchlorosilane

storage temp.

2-8°C

Quality Level

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Application

MTBSTFA + 1% TBDMSCl可作为衍生化试剂,用于:
  • 气相色谱/质谱(GC/MS)法分析人血清有机酸。
  • GC–MS-MS法分析神经毒剂及其降解产物。

General description

N-(叔丁基二甲硅烷基)-N-甲基三氟乙酰胺+ 1%叔丁基二甲基氯硅烷(TBDMS)是衍生化试剂,广泛用于气相色谱(GC)和气相色谱-质谱(GC-MS)分析。

Other Notes

发现适用于高效液相色谱液相色谱-质谱分析的理想LiChropur试剂

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

法规信息

危险化学品
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分析证书(COA)

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Gas chromatography/mass spectrometry analysis of organic acid profiles in human serum: A protocol of direct ultrasound-assisted derivatization
Zhang MJ, et al.
Rapid Communications in Mass Spectrometry, 35(17), e9149-e9149 (2021)
Mass spectrometry of anabolic steroids as their tert-butyldimethylsilyl ether derivatives.
Steffenrud, S.
Rapid Communications in Mass Spectrometry, 10, 1698-1702 (1996)
The Application of a single-column GC--MS-MS method for the rapid analysis of chemical warfare agents and breakdown products
Young SA, et al.},
Journal of Analytical Toxicology, 43(3), 179-187 (2019)
Xue Shi et al.
Journal of proteome research, 14(2), 1174-1182 (2015-01-17)
The interactions among the gut, liver, and immune system play an important role in liver disease. Probiotics have been used for the treatment and prevention of many pathological conditions, including liver diseases. Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOF
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Plant & cell physiology, 55(9), 1605-1612 (2014-06-28)
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商品

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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